聚醚胺(D230)論文PMI泡沫壳体夹层结构设计及力学性能研究.docVIP

聚醚胺(D230)论文：PMI泡沫壳体夹层结构设计及力学性能研究 【中文摘要】聚甲基丙烯酸亚胺(PMI)泡沫夹层结构整体具有很高的比强度,较大的比刚度,同时还具有优异的隔热与透波功能,越来越多地应用于大型客机、火箭整流罩、载人飞船和卫星舱段等诸多技术领域。随着航空航天科技深入发展,对于结构设计与材料的性能要求也在不断提高,使得夹层材料尤其是工艺性能十分稳定的泡沫夹层材料越来越有发展前景。本文主要研究PMI泡沫/玻璃钢复合舱段的结构与设计优化。首先以乙二胺为固化剂,并用D230(聚醚胺)对环氧树脂体系进行增韧改性。纯乙二胺固化的环氧树脂为脆性材料,当加入D230以后,由于D230的C链比乙二胺长,可以有效的增加浇注体网络空间,使交联点的密度降低。通过以上改进,制造出强度高、缺陷少、韧性好的环氧树脂浇注体。再通过三点弯曲、拉伸等实验验证得到,当D230的比例为20%的时候,浇注体的强度达到最佳,并且达到了很好的增韧效果。对断口进行扫描,进一步分析了D230的改性效果。对浇注体进行了热重法(TG)试验,得到浇注体的分解温度在260℃以上,完全达到舱段的热环境使用要求。选取聚甲基丙烯酰亚胺(PMI)作为夹层结构的芯材。制备了PMI/玻璃钢夹层结构。同时通过夹层结构侧压、三点弯曲等基本力学性能实验,对PMI泡沫夹层结构的力学性能进行了分析。同时,对纤维面板铺层、PMI泡沫密度、纤维面板的厚度等影响因素进行了规律性分析。最后,以某一型号的火箭舱段为背景,利用有限元软件Patran进行对圆柱壳和圆锥壳夹层结构进行模拟设计,并在模拟设计中对夹层结构进行了加筋处理,加大了整体的刚度。对加筋后的夹层结构进行了屈曲分析,同时考察了面板厚度、纤维铺层角度以及PMI泡沫密度对夹层结构力学性能的影响规律。 【英文摘要】Polymethacrylimide (PMI) foam sandwich structure has high specific strengths and specific stiffness, and the excellent properties of heat insulation and wave-transparent properties, so it can be widely used in the field of large aircraft, rocket fairing, spacecraft, satellite cabin and so on. With the steady development of aerospace science and technology, the demands for structure design and properties of material are urgently increased. Foam-sandwich-structured materials with very stable process performance are very remarkable and promising in wide application field.This thesis studied the structure of PMI foam / Fiber Reinforced Plastics and optimized the design of the structure.First, 1,2-ethylenediaminem was used as curing agent, epoxy resin matrix is toughened by mixing up Polyether amines (D230). Pure ethylenediamine cured epoxy resins are brittle material.After adding D230, it can effectively increase the body casting cyberspace, and decrease the density of the crosslink, for the C-chain length of the D230 is longer than that of ethylenediamine. Therefore, epoxy resin matrix with low-defect, high strength and toughness could be obtained. Then the optimization quantity of the flexible amine (D230) fillings is dete