煤焦油软沥青的流变学行为研究.docVIP

煤焦油软沥青的流变学行为研究 摘 要 流变行为是材料在熔融态和流动状态形变时的表现。它主要研究材料在应力、应变、温度、湿度、辐射等条件下与时间因素有关的变形和流动的规律。煤焦油软沥青是一种结构和组成非常复杂的混合物，其分子量和分子结构各不相同煤焦油软沥青的性质是这些不同组分的综合反映。本文以煤焦油软沥青为原料，通过反应釜对其进行空气氧化改质，得到4种软化点不同的改质沥青。分析改质沥青的软化点、甲苯不溶物、喹啉不溶物、结焦值和灰分等性能指标，并关联它们与软化点之间的内在关系；接着在高温流变仪上研究原料软沥青、4种改质沥青的流变学性能，评价在不同转速和温度下试样的粘度变化情况，获得粘温曲线，研究沥青流体的流变性能；根据试样的粘温曲线数据，计算不同软化点煤沥青的粘流活化能；为悬浮法或乳化法制备沥青微球的提供理论依据和数据。实验表明，煤焦油软沥青的粘度随温度的增大而逐渐减小，随剪切应力的增大逐渐减小，并且温度和剪切应力越大，对煤焦油沥青的影响越小。 关键词：煤焦油软沥青；流变行为；粘温曲线 Rheological behavior of soft coal tar pitch Abstract Rheological behavior of the material in the molten state when the state of deformation and flow performance. It mainly studies the material under stress, strain, temperature, humidity, radiation and other conditions of the law of the deformation and flow of time-related factors. Soft coal tar pitch is a very complex mixture of structure and composition, the molecular weight and molecular structure varies, the nature of soft coal tar pitch is a comprehensive reflection of these different components. In this paper, soft coal tar pitch as a raw material, in this paper, soft coal tar pitch as a raw material, its modification by air oxidation reactor, to obtain four kinds of softening point different modified bitumen. Analysis of modified bitumen softening point, toluene insoluble, quinolone insolubles and ash coking values and other performance indicators, and associate them with the softening point of the intrinsic relationship between; Then study materials soft asphalt, rheological properties of four kinds of modified asphalt at high temperature rheometer, viscosity was evaluated at different speeds and temperatures of the sample, obtain viscosity-temperature curve, rheological properties of bitumen fluid; According to data of the sample viscosity-temperature curve, Calculate different softening point coal tar viscous flow activation energy; A suspension or emulsified asphalt prepared microspheres provide a theoretical basis and data. Experimental results show that t