Mg-Ca基合金研究..doc

Mg-Ca基合金研究 1．Mg-Ca二元合金相图： Ca在镁中的溶解度在515oC时是1.34%（重量），但是到200oC时几乎为0。 铸态相结构：α-Mg+(α-Mg, Mg2Ca)共晶 1. A Study of Homogenization and Precipitation Hardening Behaviour of Mg-Ca-Zn Alloys A thesis presented to the University of Waterloo in fulfillment of the thesis requirement for the degree of Master of Applied Science In Mechanical Engineering Waterloo, Ontario, Canada, 2008 Ashkan Shadkam 一．合金成分： 二． Mg-Ca binary alloy: heat treatment: Mg-Ca-Zn ternary alloy: heat treatment: 组织腐蚀剂： One etchant however, acetic glycol（醋酸乙二醇）（1ml硝酸，20ml醋酸，60ml乙二醇和20ml水）(1 ml HNO3, 20 ml acetic acid, 60 ml ethylene glycol and 20 ml water) reveals grain boundaries and is suitable for revealing more microstructural details. Dilute HNO3 is also used [Levi et al. 2006]. Although two etchants do not differ much in terms of revealing microstructural characteristics, HNO3 reveals needle-shaped features not exposed by acetic glycol etchant. Mg-2.5Ca 铸态、固溶及时效组织 铸态组织 铸态组织 固溶态组织 硝酸腐蚀 抛光 时效1750C6小时 Mg-2.5Ca 时效硬化曲线 铸态Mg-2.5Ca XRD Mg-2Ca-1Zn 铸态、固溶及时效组织、时效硬化曲线 Mg-2Ca-1Zn 时效硬化曲线 Mg-2Ca-2Zn 铸态、固溶及时效组织、时效硬化曲线 Mg-2Ca-2Zn 铸态组织，所有的为抛光 三个合金硬化曲线比较 (a) Mg-2.5Ca, (b) Mg-2Ca-1Zn, ( c) Mg-2Ca-2Zn 结论：加Zn之后，大大增强了Mg-Ca合金的时效硬化效应。 7.2 Suggestions for the Future Work The recommendations to further study microstructural characteristics and aging response of the alloys are summarized as follows: ??TEM investigations of the as-cast and homogenized alloys are recommended. In the binary alloy it will help determine microstructural changes in the eutectic mixture. In the case of ternary alloys, studying grain boundary particles after homogenization heat treatment with the aid of diffraction patterns, will determine how zinc participate in the Laves phases in these particle. ??For each alloy of the present investigation, wi