液相络合-铁屑还原-酸吸收回收法脱除烟气中NOX08.docVIP

液相络合-铁屑还原-酸吸收回收法脱除烟气中NOX 马乐凡 尹奇德 郭振华 宋剑飞 （长沙理工大学化学与环境工程系 湖南长沙 410076） 摘要：提出了“Fe2+螯合剂吸收-铁屑还原-酸吸收”回收法脱除烟气中NOx的新工艺，在鼓泡反应器中研究了铁屑脱氮过程的影响因素，确定了脱氮过程的合适工艺条件，并对络合脱氮液的再生和循环利用进行了研究。结果表明：过程的最佳工艺参数为：络合脱氮液中Fe2+EDTA浓度20mmol·L-1，pH值6.0，温度65℃；在此条件下，用两个反应器串联，对O2含量为10.5%的模拟烟气可取得90%以上的脱氮效率；过滤出络合脱氮液中的铁沉淀物即完成了络合脱氮液的再生，并可恢复其脱氮性能，经过反复多次脱氮和再生以后，脱氮效果能够保持稳定。 关键词：氮氧化物；络合吸收；铁屑还原；脱氮液再生 Removal of NOx from flue gas with the recovery process of absorption with acid following complex in aqueous solution and reduction with iron filings Ma Lefan, Yin Qide, Guo Zhenhna, Song Jianfei. (Department of Chemical Environmental Engineering, Changsha University of Science and Technology. Changsha, China. 410076) Abstract: A novel recovery process for removal of NOX from flue gas with the sequence of absorption with acid following complex with ferrous chelate in aqueous solution and reduction with iron filings is proposed. The parameters influencing the NOx removal efficiency are investigated in a bubble column. The optimal conditions for removal of NOx is established. The regeneration and utilization circularly of the absorption solution is studied also. The results show that the optimal conditions for removal of NOx from flue gas with the process of iron filings reduction following liquid phase complex in a bobble column is Fe2+EDTA concentration 20 mmol稬-1n, pH6, 65℃. Under the circumstances, NOx removal efficiency for flue gas containing O2 10.5% exceeds 90% in two series absorbers. The ability of absorption solutions for NOx removal can be recovered completely after filtrated to separate the iron precipitated compounds away, and the NOx removal efficiency keeps steady after regeneration many times. Keywords: nitrogen oxides; complex and absorption; reduction with iron filings; regeneration of the absorption solution 燃烧产生的NOX是大气的主要污染物之一，已商业化的烟气NOX脱除技术主要有选择性催化还原法和选择性非催化还原法，这2种方法的投资和运行费用较高。因此，开发简单、廉价、适用的NOx控制新技术是近30年来大气污染控制领域的一个热门课题。 烟气中的NOx95%左右是NO，而NO在水和碱液中的溶解度很低，因此，用普通湿式洗涤法几乎不能去除烟气中的NOx。日本和美国[1~4]从20世