嵌段共聚物自组装纳米薄膜[精选].ppt

Thank you! Any question * Free-Standing Nanomaterials from Block Copolymer Self-Assembly llye88 化学所 Main Reference Outline Introduction Experimental Part Results and Discussion Conclusions Innovations and Problems References 1. Introduction Amphiphilic block copolymers (BCs) could control material interfaces . The 3D construction is directed by the assembly of BCs micelles prepared in situ during the spin-coating of the block copolymer solution. BCs in selective solvent lead to the preparation of core-shell micelles with a dense insoluble core and a diffuse shell partially swollen by the solvent a dense insoluble core内核 micelles a diffuse corona核冠 In this work，the preparation of stable nanostructure assemblies in one step from homogeneous solutions of ABA triblock copolymers. The success of this strategy is essentially due to the design of very stable micelles prepared and self-assembled in situ in few seconds by solvent evaporation Self-Assembly Nanomaterials The glassy PSAN blocks will enable the formation of compact aggregates constraining the micelles to be kinetically frozen at room temperature whereas the flexible PEO block will enable the dynamic transitions between looped and bridged chain conformations. looped bridged Photon Cross Correlation Spectroscopy Photon Cross Correlation Spectroscopy（PCCS），光子交叉相关光谱法 PCCS已用于纳米颗粒粒径测量,其技术日益成熟并成为纳米颗粒粒径测量的有效方法。其测量原理是建立在颗粒的布朗运动之上。随着颗粒的布朗运动,散射光强围绕某一平均值不断起伏涨落。 PCCS可以直接测试高浓度试样而不需要稀释。测量结果完全真实的反映了被测试样品的实际粒度及分布状态 PCCS测定的参数为：平均粒径和多分散指数 吴立敏，王晓艳. 纳米、亚微米颗粒粒度的测量——光子相关光谱法,《上海计量测试》， 2003年 30卷 3期 2.Experimental Part Sythesis of the Triblock Copolymer a. Esterification PEO+Acryloyol Chloride（丙烯酰氯） PEO-acrylate(I) b. Intermolecular Radical Addition I+MAMA-SGI alkoxyamine macroalkoxyamine-based PEO(II) c. Preparation of Triblock Copolymer II+Styrene+Arylonitrile P(St317-co-AN262)-b-PEO795-b-P(St-co-AN)