ppt课件-chemistry332 basic inorganic chemistry i i（chemistry332基本无机化学我我）.pptVIP

The Mond Process Hemoglobin and Heme Course Outline Formation and Reactions of TM Complexes Where do we start? Stable vs. UnstableInert vs. Labile TM Aqua Complexes Look at the reaction coordinate diagram… Kinetics vs. Thermodynamics Conclusions from these examples. Stepwise formation constants The Pearson LA/LB “Hard”/“Soft” Approach Chelate Effect Reactions of Coordination Complexes Rxns of Octahedral Complexes Dissociative Mechanism Associative Mechanism Telling the difference… Solvents and Water!! Solvent and Associative Processes Looking at the structures… ML6 Preferred Mechanism Charge/