研究生用--化工热力学-补充习题[精选].doc

化工热力学习题研究生用 第章习题 A 4-m3 storage tank containing 2 m3 of liquid is to be pressurized with air from a large, high-pressure reservoir through a valve at the top of the tank to rapid ejection of the liquid(see figure) the air in the reservoir is maintained at 100 bar and 300K. The gas space above the liquid contains initially air at 1 bar and 280K. When the pressure in the tank reaches 5 bar, the liquid transfer valve is opened and the liquid ejected at the rate of 0.2 m3/min while tank pressure is maintained at 5 bar. What is the air temperature when the pressure reaches 5 bar and when the liquid has been drained completely? Neglect teat interactions at the gad-liquid and gas tank boundaries. It may be assumed that the gas above the liquid is well mixed and that air is an ideal gas with a constant value of Cv = 20.9 J/mol(K 1-2. We have liquid ethane at 1 bar pressure what is the maximum temperature the liquid ethane can be heated before it reaches the limits of stability? Use the Peng-Robinson equation of state with the following data Tc = 305.4 K Pc= 48.8 bar ω= 0.098 Tb=184.5 K(at 1.013 bar). 1-3. From the report of a thermodynamicist:” while relaxing near a large tank of nitrogen gas (A) at 687 kN/m2 and 298K, I began reviewing some of my knowledge in thermodynamics. A rather interesting experiment suggested itself and I thought I would compare theory with real data (see figure). I first filled B with nitrogen gas at 101 kN/ m2 and 298K and connected it as shown. Then working quickly, I opened valve C (with D closed ) and allowed the pressures in B to its original pressures in Band A to equalized. Then, working quickly, then, I quickly closed C and opened D to flow down vessel B to its original pressure. I repeated this sequence a number of times. Tank A was so large that I did not cause any significant drop in pressure in it by my experiments. Second, I pressurized and blew B so rapidly that little heat transfer probably occurred during this time