【2017年整理】电子专业论文.docVIP

锂离子电池尖晶石氧化锰锂? 正极材料的研究? 摘???要? ? 锂离子电池在现代新能源中扮演着越来越重要的角色，在目前商品化锂离子电池中，正极材料主要还是氧化钴锂，而钴的数量有限，锂离子电池消耗钴量不少。另一方面，钴的价格最高，镍的价格其次，而锰的价格是最低的，由于我国的锰储量最丰富，应用氧化锰锂材料可以大大降低成本，而且锰无毒，污染小人们对回收利用问题在一次锂电池中已经积累丰富的经验，因此氧化锰锂成为正极材料研究的热点。锰氧化材料比较多，主要有三种结构：隧道结构，层状结构和尖晶石结构。研究氧化锰锂材料主要有尖晶石结构的LiMn2O4，Li4Mn5O9和Li4Mn5O12，以及层状结构的LiMnO2。? 对于LiMn2O4,通过引入适当的杂原子和采用新的溶胶—凝胶法制备可以有效的克服Jahn-Teller效应所造成的容量衰容减现象。当然通常制备LiMn2O4的方法是固相制备法。Li4Mn5O9,Li4Mn5O12可以用低温方法合成能作为锂离子电池理想的正极材料。层状结构的LiMnO2的容量比目前常用的正极材料质量容量均要高，可达270mAh/g，而且循环性能比较理想。随着电子技术的发展以氧化锰为正极锂离子电池将得到广泛的应用。? ? 关键词：锂离子电池；正极材料；制备；发展；应用 ? ?II? Research?the?spinel?structure?of?lithium?manganese?oxide?as?the?anode?electrode?in?lithium-ion?battery? Abstract? ? Lithium-ion?batteries?in?the?modern?new?energy?play?an?increasingly?important?role?in?the?current?commercial?lithium-ion?batteries,?cathode?materials?of?lithium?cobalt?oxide?is?mainly,?but?a?limited?number?of?cobalt,?cobalt?lithium-ion?battery?consumption?a?lot.?On?the?other?hand,?the?highest?price?of?cobalt,?nickel?prices?followed,?but?the?price?is?the?lowest?manganese,?because?of?Chinas?most?abundant?reserves?of?manganese,?the?application?of?lithium?manganese?oxide?can?significantly?reduce?material?costs,?and?manganese?non-toxic,?pollution,?recovery?of?people?Utilization?in?a?lithium?battery?has?been?accumulated?rich?experience,?so?as?cathode?material?of?lithium?manganese?oxide?of?research.?More?manganese?oxide?materials,?there?are?three?structures:?the?tunnel?structure,?layered?structure?and?spinel?structure.?Study?of?lithium?manganese?oxide?spinel?structure?materials?are?LiMn2O4,?Li4Mn5O9?and?Li4Mn5O12,?and?the?layered?structure?of?the?LiMnO2.?????For?LiMn2O4,?by?introducing?appropriate?complex?atoms?and?introduction?of?new?sol?-?gel?method?can?effectively?overcome?the?Jahn-Teller?effect?caused?by?the?reduced?capacity?of?the?capacity?decay?phenomenon.?Of?course,?the?method?is?usually?prepared?by?solid?phase?LiMn2O4?preparation?method.?Li4Mn5O9,?Li4Mn5O12?can?be?synthesized?at?low?temperature?can?serve?