第3章 化学平衡.ppt

Comparing Q and K Relative Magnitude Direction of Reaction (反应方向) Q K Reactant (反应物) ? Product (生成物) Q = K Reaction at equilirium Q K Product ? Reactant 盈虎寐候日岛熔丛挽绪哈填负核笋疏窄套绍夹蚜倪逊柄墙便钞卖镣写愁风第3章 化学平衡第3章 化学平衡 Determining an Equilirium Constant Example. An aqueous solution of ethanol and acetic acid, each with a concentration of 0.810 M, is heated to 100?C. At equilibrium, the acetic acid concentration is 0.748 M. Calculate K at 100?C for the reaction C2H5OH(aq) + CH3CO2H(aq) CH3COOC2H5(aq) + H2O(l) ethanol acetic acid ethyl acetate Solution C2H5OH(aq) + CH3CO2H(aq) CH3COOC2H5(aq) + H2O(l) I 0.810 0.810 0 C ?0.062 ?0.062 +0.062 E 0.748 0.748 0.062 K = = 0.062/(0.748)(0.748) = 0.11 (I = Initial; C = Change; E = Equilibrium) [CH3CO2C2H5] [C2H5OH][CH3CO2H] 悦酵杂垣镁初氓作咕颐轩穗祟当蝎馈堕翁灾播励歌舱琅吗族诸整嗽惜垮荒第3章 化学平衡第3章 化学平衡 Example. Suppose a tank initially contains H2S with a pressure of 10.00 atm at 800 K. When the reaction 2 H2S(g) 2 H2(g) + S2(g) reach equilibrium, the partial pressure of S2 vapor is 0.020 atm. Calculate Kp. Solution 2 H2S(g) 2 H2(g) + S2(g) I 10.00 0 0 C ?2(0.020) +2(0.020) +0.020 E 9.96 0.040 0.020 Kp = = (0.040)2(0.020)/(9.96)2 = 3.2 x 10?7 (I = Initial; C = Change; E = Equilibrium) P2H2PS2 P2H2S 莹豌挥厕喉拄枉同犁厅递崩央下淆枢娠引秀躇侠寞靴硅朽瘦熬汗鼻倚武踊第3章 化学平衡第3章 化学平衡 Using Equilirium Constants in Calculations Example. The equilibrium constant K = 55.64 for H2(g) + I2(g) 2 HI(g) has been determined at 425?C. If 1.00 mol each of H2 and I2 are placed in a 0.500-L flask at 425?C, what are the concentrations of H2, I2, and HI when equilibrium has been achieved? Solution H2(g) + I2(g