WOZnO复合光催化剂的制备及其光催化性能.docVIP

WO3/ZnO复合光催化剂的制备及其光催化性能 摘要：采用沉淀-研磨法制备了一系列不同WO3含量的WO3/ZnO复合光催化剂, 应用N2物理吸附、X射线衍射、扫描电镜、傅里叶变换红外光谱、紫外-可见光谱和光致发光谱等手段对催化剂进行了表征，并以λ=365nm的紫外光为光源，评价了该催化剂光催化降解酸性橙II的活性，考察了WO3的复合对WO3/ZnO样品光催化性能的影响。结果表明，当复合2%WO3, 并于600℃焙烧时，所制备的WO3/ZnO催化剂活性最高, 比纯ZnO提高了约一倍。合适的煅烧温度可以提高催化剂结晶度, 而WO3的复合可抑制ZnO晶粒的长大，提高催化剂比表面积和改善催化剂表面羟基数量，并可抑制光生电子与光生空穴的复合，从而显著提高其光催化脱色活性。 关键词：氧化钨; 复合; 氧化锌; 光催化; 酸性橙II Preparation of WO3/ZnO Composite Photocatalyst and Its Photocatalytic Performance Abstract: A series of WO3/ZnO composite photocatalysts with different WO3 concentrations were prepared by a precipitation-grinding method followed by calcination at different temperatures. The prepared samples were characterized by N2 physical adsorption, X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, UV-visible spectroscopy, and photoluminescence spectroscopy. The photocatalytic activity of the samples was evaluated by photocatalytic degradation of acid orange II under UV light (λ=365nm) irradiation. The results showed that at the optimal calcination temperature of 600℃, the WO3/ZnO composite photocatalyst with 2 wt% concentration of WO3 showed about doubled photocatalytic activity compared to pure ZnO. The increase in the photocatalytic activity could be attributed to the coupling of WO3, which suppressed the growth of ZnO particles, increase of the surface area and increased amount of surface OH groups of the sample. The presence of WO3 also restrained the recombination rate of e?/h+pairs. Key words: tungsten oxide；coupling；zinc oxide；photocatalysis；acid orange II 半导体光催化氧化技术具有操作简单、反应条件温和、能耗低及二次污染少等优点，因而在环境治理领域引起广泛关注[1-3]。ZnO是一种禁带宽度约为3.1eV的n型半导体, 广泛应用于纤维、化妆品、陶瓷、玻璃和建材等领域, 同时它具有一定的光催化性能, 可将各种易挥发性有机污染物最终氧化为CO2和H2O等无机物, 也可氧化除去水中几乎所有的有机污染物, 因此它的光催化作用近来引起人们的重视[4-5]。与TiO2相比, ZnO光催化剂的催化效率不高[6]，且易发生光腐蚀而导致稳定性低。目前, 提高ZnO光催化性能的主要方法有：(1) 通过制备方法改变其物理结构性质，如改变其粒径或形貌[7~9]；(2) 采用表面贵金属沉积[10~11]、金属离子掺杂[12]、半导体复合[13~14]或非金属掺杂[15]等方法改变其能级结构, 提高其光催化效率。其中半导体复合可利用两种半导体的互补性质，即两种半导体材料之间的能级差有效分离电荷，达到促进光生电子和空穴对的