利用工业木质素制备高性能球形木质素吸附剂的研究.docVIP

利用工业木质素制备 高性能球形木质素吸附剂的研究 摘要：以工业木质素为原料，添加分散剂十二烷基硫酸钠及交联剂环氧氯丙烷，采用“反相悬浮法”制备出球形木质素珠体。并进行球形木质素珠体的理化性能分析及其对金属离子吸附的性能研究。 首先采用单因素实验和正交实验优选球形木质素制备的条件，结果表明最佳制备条件为：5g工业木质素溶于50ml碱液；油水相比为3∶1；分散剂十二烷基硫酸钠0.6g；交联剂环氧氯丙烷3.0g；搅拌速度为200～250r ·min-1；采用两步升温，该方法制备出的球形木质素珠体得率达87.75%，其湿视密度1650.0kg·m-3，湿真密度1006.4kg ·m-3，含水率81.48%。球形木质素珠体为非晶态结构，结构松驰，孔隙度较高，对Pb2+和Cr6+的吸附量分别达到8mg·g-1和2mg·g-1。 由于所制备的球形木质素材料耐酸、碱及有机溶剂性能强，因此有望进一步改性制备高性能、重复利用的木质素基吸附剂，并可广泛应用与工业废水的处理及资源回收利用。 关键词：工业木质素； 反相悬浮原理； 球形颗粒； 吸附剂 Preparation the High-performance Spherical Lignin Adsorbent with Technical Lignin Abstract: With the industrial lignin as material, adding dispersant SLS and cross linker ECH preparing the spherical lignin beads (SLB) by reversed phase suspension technique. And, for the physical-chemical properties and metal ions adsorption studies of SLB. First, SLB was prepared by the signal-factor and orthogonal experiments to optimize the preparation conditions, results show that the best preparation conditions: dissolve in water 5g technical lignin 50ml, 3:1 of the volume ratio of the transformer oil and water, 0.6g of SLS, 3.0g of ECH dosage at the agitation speed of 250 r·min-1 at 60℃for 1h and subsequently at 90℃for anther 1 h. The ideal SLB with the 87.75% of the yield, and 1650.0 kg·m-3 of the wet eye density and 1006.4 kg ·m-3of the wet real density, 81.48% of water retention could be obtained under this conditions. SLB is amorphous structure, structure relaxation and high porosity, the adsorption capacities for Pb2+ and Cr6+ were 8mg/g and 2mg/g，respectively. SLB material has a better performance on acid-resisting, alkali-resisting and Organic solvents resistance. Consequently, a further modification to the preparation of high-performance and reuse lignin base adsorbent, and it can be widely applied in industrial wastewater treatment and resource recycling. Key words: Technical lignin, reversed phase suspension technique, spherical lignin beads, adsorbent 　　　　　　　　　　　 目　　录 摘要