chem5_jun13_qp-aqa.doc

For Examiner’s Use Centre Number Candidate Number Surname Other Names Examiner’s Initials Candidate Signature Question Mark General Certificate of Education Advanced Level Examination June 2013 1 2 Chemistry CHEM5 3 4 5 Unit 5 Energetics, Redox and Inorganic Chemistry 6 Wednesday 19 June 2013 9.00 am to 10.45 am 7 8 For this paper you must have: l the Periodic Table/Data Sheet provided as an insert (enclosed) l a calculator. TOTAL Time allowed l 1 hour 45 minutes Instructions l Use black ink or black ball-point pen. l Fill in the boxes at the top of this page. l Answer all questions. l You must answer the questions in the spaces provided. Do not write outside the box around each page or on blank pages. l All working must be shown. l Do all rough work in this book. Cross through any work you do not want to be marked. Information l The marks for questions are shown in brackets. l The maximum mark for this paper is 100. l You are expected to use a calculator, where appropriate. l The Periodic Table/Data Sheet is provided as an insert. l Your answers to the questions in Section B should be written in continuous prose, where appropriate. l You will be marked on your ability to: – use good English – organise information clearly – use scientific terminology accurately. Advice l You are advised to spend about 70 minutes on Section A and about 35 minutes on Section B. (JUN13CHEM501) WMP/Jun13/CHEM5 CHEM5  2 Do not write outside the box Section A Answer all questions in the spaces provided. 1 (a) Define the term lattice enthalpy of dissociation. (2 marks) 1 (b) Lattice enthalpy can be calculated theoretically using a perfect ionic model. Explain the meaning of the term perfect ionic model. (1 mark) (Extra space) 1 (c) Suggest two properties of ions that influence the value of a lattice enthalpy calculated using a perfect ionic model. Property 1 Property 2 (2 marks) (02) WMP/Jun13/CHEM5  3 Do not write outside the box 1 (d) Use the data in the ta