持久性有机污染物的环境界面行为.docVIP

【Abstract】 Persistent organic pollutants (POP) are highly lipophilic and 亲脂性的，亲脂的 chemically stable. Photodegradation may be one of the dominant abiotic 光降解，光降解作用 显性的，占优势的 非生物的，无生命的 transformations of the chemicals. Therefore, it is of great importance to 转变，转换 investigate the photolytic behavior of POP in the environment. Previous 调查研究 光解的 studies focus on the photodegradation of POP in aqueous phase and in 水的，水般的 相的，相位 水相 atmosphere. The photolytic behavior of POP at the interfacial 界面的 environment is investigated in this study.Spruce (Picea abies (L.) Karst.) 云杉 挪威云杉 喀斯特地形 needles were exposed exhaust gas containing polychlorinated 针叶型 废气 多氯化的 dibenzo-p-dioxins and dibenzofurans (PCDD/F) and polycyclic aromatic 二噁英 二苯并呋喃 多环的 芳香的 hydrocarbons (PAH) generated by combustion of polyvinyl chloride 烃类 产生的，制作 燃烧，氧化 高分子聚氯乙烯 (PVC), wood, high-density polyethylene (HOPE), and styrene. 高密度聚乙烯 苯乙烯 Photodegradation of PCDD/F and PAH adsorbed on spruce needles under 吸附了的 针叶云杉 sunlight irradiation was studied. The factors of sunlight irradiation on the 照射，发光，发射 surfaces of spruce needles were taken into consideration when investigating the kinetic parameters.The photodegradation of the 70 活跃的 参数，参量 PCDD/F and the 18 PAH follows pseudo-first-order reaction kinetics. The 伪一级反应 反应动力学 photodegradation half-lives range between 20 h and 50 h for PCDD/F and 半衰期 between 15.8 h and 75.3 h for PAH. Thus in the field conditions, 在野外实地的 photodegradation plays a major r