活性炭对水中微量Cr(Ⅲ)的吸附研究.docVIP

用活性炭如何吸附水中微量Cr（Ⅲ）的研究 活性炭对水中微量Cr（Ⅲ）的吸附研究黄? 岩?? 曾崇余（南京工业大学化学化工学院，江苏? 南京 210009）摘要? 采用两种不同浓度的HNO3及NaOH溶液对片状椰壳活性炭进行改性，考察了改性前后的活性炭在不同吸附时间、Cr（Ⅲ）溶液初始浓度和pH等条件下对微量Cr（Ⅲ）的吸附性能，并通过SEM、BET、Boehm滴定等手段表征了改性前后的吸附剂，探讨了吸附机理。研究表明，片状椰壳活性炭经上述改性后，在pH6的水溶液中对Cr（Ⅲ）的吸附速率、平衡吸附量和去除率均比改性前有所增加，尤其经浓HNO3改性的活性炭(AC2)吸附性能提高更为显著。在pH为4、Cr（Ⅲ）溶液为5～20 mg/L、AC2用量为8 g/L时，对Cr（Ⅲ）的去除率达到96％以上，是去除水中微量Cr（Ⅲ）的优良吸附剂。SEM、BET表征表明，改性后的活性炭(AC1和AC2)表面形貌发生显著变化，比表面积有所降低，中孔和大孔数量有所增加，总孔容变化不大。Boehm滴定表明，经HNO3氧化后，活性炭表面含氧官能团数量增加，经浓HNO3氧化后官能团数量增加显著，经NaOH二次改性使这些官能团转化为带负电的基团，并通过静电吸附实现对Cr（Ⅲ）的去除。活性炭表面含氧官能团的增加是改性活性炭对Cr（Ⅲ）吸附性能提高的主要原因。关键词? 活性炭? 改性? Cr（Ⅲ）? 吸附 Research on adsorption of Cr（Ⅲ）from aqueous solution by activated carbon? Huang Yan? Zeng Chongyu. (College of Chemistry and Chemical Engineering，Nanjing University of Technology，Nanjing Jiangsu 210009)?Abstract：Coconut shell activated carbon was chemically modified with different concentration of nitric acid and sodium hydroxide. Adsorption of Cr（Ⅲ）on activated carbons before and after modification was studied under different time, Cr（Ⅲ）concentration and pH. Through characterizing of activated carbons by BET, SEM and Boehm titration, adsorption mechanism of Cr（Ⅲ）was discussed. Results showed that, when pH was less than 6, activated carbons had a much better effect in adsorption velocity, amount and removal rate after modification. Activated carbon modified by concentrated HNO3 was a fine absorbent to Cr（Ⅲ）, when its concentration was 8 g/L and pH was 4, removal rates were more than 96% with concentrations from 5 to 20 m g/L of Cr（Ⅲ）. Results of SEM and BET showed that, micrographs of modified activated carbon changed much, the surface area decreased, the number of mesopore increased, but the total pore volume changed little. Results of Boehm titration showed that, modified by HNO3, the number of surface oxygen groups increased. After modification by NaOH, these oxygen groups were changed to electronegative groups and removed Cr（Ⅲ）through electrostatic adsorption. The main cau