火焰原子吸收光谱法快速测定人参中钙镁.docVIP

火焰原子吸收光谱法快速测定人参中钙镁 首席医学网 ???? 2006年05月27日 09:47:54 Saturday?? ? 中华临床医师杂志征稿 神经性疼痛疾病诊疗班 胸部疾病影像诊断班 心律失常现代诊疗会议 医学类核心期刊征稿 治未病调理师培训班 医院药学新进展会议 第13届国际急诊学大会 四届中华消化病学讲坛 2010中国介入治疗论坛 全国疑难重症肝病大会 青光眼规范诊疗论坛 2010世界心脏病学大会 全国静脉治疗护理论坛 股骨头坏死修复论坛 作者：刘立行 张春光  ? 加入收藏夹 【关键词】? 火焰原子吸收光谱法 　　摘? 要? 目的与方法 用悬浮液技术及非完全消化法2种样品处理技术分别处理人参样品，建立了悬浮液技术或非完全消化-火焰原子吸收光谱法快速测定人参中钙、镁的分析方法。结果与结论 试验表明，在悬浮液中加入适量盐酸可显著提高被测元素的吸光度，试液的黏度与空白溶液的一致,无背景吸收干扰。以La3+作为释放剂，用工作曲线法测定。测定结果的RSD值小于2.6%，测定结果与灰化法一致，RSD小于±2.3%。方法简便、准确。 　　关键词? 火焰原子吸收光谱法；悬浮液技术；非完全消化法；人参；钙；镁 　　Rapid determination of calcium,magnesium in ginseng by flame atomic absorption spectrometry 　　LIU Lixing ,ZHANG Chunguang 　　(Department of Applied Chemistry,Liaoning University of Petroleum Chemical Technology,Fushun 113001,China) 　　Abstract? Objective and Methods? Treat the ginseng sample with two pretreatment techniques of suspension technique and incomplete digestion method,respectively.A FAAS method for rapid determination of calcium and magnesium in ginseng with suspension technique or incomplete digestion method has been developed. Results and Conclusion The test indicated that in suspension method absorbanses of determined element were markedly increased by adding suitable amount of hydrochloric acid into the test solution, viscosity of test solution is identical with its blank solution and there is not background absorption interference.La3+ was used as releasing agent.The working curve method was used for the demination.The relative standard deviations were less than 2.6%.The determination results were consistent with those obtained by ashing method.The relative errors between them were less than ±2.3%.This method was convenient and accurate. 　　Key words? flame atomic absorption spectrometry；suspension technique；incomplete digestion method；ginseng；calcium；magnesium 　　近代医学证明，微量元素与药理作用相关，了解药物中微量元素含量有助于研究药物的药理作用。人参是一种珍贵的滋补药材，主补五脏，可使人延年益寿。药材样品的前处理方法通常为灰化法［1］、消化法［2］。缺点均是耗时长，一般需4 h以上，灰化法有时需几十小时。近年来微波消解技术已应用于人参样品的前处理［3］，大大加快了分析速度。本文分别用悬浮液技术及