国科会专题研究计画成果报告撰写格式说明.docVIP

行政院國家科學委員會補助專題研究計畫 (成果報告 □期中進度報告 PVA 交聯對幾丁聚醣混合矩陣式基材之銅離子 吸附/脫附程序影響之探討 (The effects of PVA crossslinking on the Cu2+ adsorption/desorption of chitosan mixed matrix scaffolds) 計畫類別：(個別型計畫 □整合型計畫 計畫編號：NSC 99－2221－E－163－003－ 執行期間：99年08月01日至100年07月31日 執行機構及系所：中國科技大學通識教育中心 計畫主持人：謝子陽 共同主持人： 計畫參與人員：謝子陽、洪敏玲、黃靖軒 成果報告類型(依經費核定清單規定繳交)：(精簡報告 □完整報告 本計畫除繳交成果報告外，另須繳交以下出國心得報告： □赴國外出差或研習心得報告 □赴大陸地區出差或研習心得報告 □出席國際學術會議心得報告 □國際合作研究計畫國外研究報告 處理方式：除列管計畫及下列情形者外，得立即公開查詢 □涉及專利或其他智慧財產權，□一年□二年後可公開查詢 中 華 民 國 100年 10 月 11 日 中文摘要： 本研究為結合對重金屬離子具有離子交換能力之離子交換樹脂(Amberjet 1200H, Styrene divinylbenzene copolymer, Rohm Haas, ID: 0.78 mm)以及中分子量之幾丁聚醣粉末，以製備出多孔隙度混合矩陣式立體結構的吸附基材，其對廢水中銅離子之移除能力。經由氮氣吸附法量測出混合矩陣基材的比表面積，另外經由電子顯微鏡照片清楚觀測出離子交換樹脂於幾丁聚醣立體結構中分布，有利於銅離子質傳進入基材內部，並與幾丁聚醣官能基發生螯合作用，以及與離子交換樹脂進行離子交換反應。另外經由試驗發現，吸附過程中銅離子溶液之酸鹼值，吸附過程中銅離子與水溶液中的氫離子同時對吸附官能基(幾丁聚醣的氨基以及離子交換樹脂的磺酸基)競合現象。另外經由量測銅離子平衡濃度以及混合矩陣式基材於不同銅離子初始濃度下的銅離子平衡吸附量，可得到等溫吸附曲線。ixed matrix scaffolds were synthesized by uniformly distribution of ion exchange resins (H+ form Amberjet, ID 780 μm) into the stereo-structural chitosan matrix and then crosslinked by polyvinyl alcohol solutions. The scaffolds were used for the removal of copper ions from waste water. Specifically, ion exchange resin particles suspending in a 2 wt% of viscous chitosan solution were filled with cylindrical aluminum containers to prepare chitosan mixed matrix scaffolds through the freeze-gelation process. The internal surface area of mixed matrix scaffolds was evaluated and measured by N2 adsorption/desorption processes. The adsorption processes were performed by adsorption copper ions of waste water onto the amine functional groups (-NH2) exposed to the external and porous stereo-structural surfaces of chitosan matrix as well as the sulfonate functional groups at the outer surface of ion exchange resins respectively. Results of continuous batch adsorption/desorption experiments could be explained by both copper ions and hydronium ions compete for av