气相吸附钾的烧结矿的冶金性能影响研究.docxVIP

气相吸附钾的烧结矿的冶金性能影响研究摘 要：模拟首钢的高炉中钾循环富集的实际情况，使用垂直电阻炉完成烧结矿对单质钾的气相吸附，得到的富钾烧结矿用于吸附分析以及冶金性能的实验检测。XRD和电镜扫描分析得到钾在烧结矿中的存在形式和分布状态，为冶金性能分析提供了理论支持；烧结矿冶金性能实验研究钾对烧结矿冶金性能的影响，并从机理上进行了解释分析。结果表明： 随钾的富集倍数的增加，即烧结矿中富集钾的含量的增加，烧结矿还原度从73.1%增加为81.3%；钾的存在会使还原粉化指数RDI+3.15降低，但随着钾含量在0.10%-0.18%继续增加时，RDI+3.15又逐渐升高；富钾后的烧结矿其软化开始温度降低，软熔温度区间变宽。关键词：钾；气相吸附；烧结矿；冶金性能Effect Research of Metallurgical Properties for the Sinter Enriched Potassium by Gas Phase Adsorption Method Yan Zhi-wu1 Li Xin-yu1 Zhang Jian-liang1 Yuan Xiang1 Gao Bin1 Zhang He-shun2（1 School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing,Beijing 100083, China; 2 Shougang Jingtang United Iron Steel Co. Ltd, Hebei Tangshan 063200, China.）Abstract：The actual situation of cycle and enrichment for potassium in Shougang BF is simulated, the adsorption of sinter on potassium (K) was completed by a vertical tube furnace, the sinter enriched K is used to adsorption analyses and the test detection of metallurgical properties. The XRD and SEM-EDS show the existing forms and distribution state of the K in the sinter, and provide theoretical support for metallurgical properties analysis. the impacts of the K for metallurgical properties of sinter is researched by the metallurgical property test, and they are explained and analyzed from theory. The results showed that, with the increase of the enrichment factor, sinter reducibility increased from 73.1% to 81.3%; the existence of the K make RDI+3.15 decreased, but with the increase of the amount of potassium-rich from 0.10% to 0.18%, the RDI+3.15 increase gradually; for softening-melting properties, the K make apparent initial softening temperature (T10) lower, and make soft melting temperature range wide. 在目前严峻的钢铁形势下，烧结原料具有种类多、品质差的特点，而且随着高炉冶炼技术的进步，排除了许多干扰高炉生产的因素，有害元素钾对高炉冶炼的危害逐渐暴露出来。钾在铁矿石中的含量较少，其影响较为微弱，但钾在高炉中会以单质蒸汽的形式进行循环富集作用[1-3]，这会对高炉冶炼产生较大的影响[4]。而烧结矿是高炉中的主要原料，占高炉含铁原料的80%左右[5]，其冶金性能越来越成为高炉冶炼的一个重点关注方向。所以，很有必要去研究循环富集的钾与烧结矿冶金性能之间的影响关系。早在二十世纪七八十年代的时候，国内外的研究工作者就注意