Maximum Valency Lattice Gas Models Lorentz Center最高的格子气模型洛伦兹中心.pptVIP

Discussant: Srikanth Sastry JNCASR, Bangalore, India Dynamical heterogeneities in Chemical gels and?attractive colloids Antonio Coniglio Summary of main points in Antonio’s talk. What is new and interesting. Discussion of these in the context of glass formers and gel formers. Outline Systems of interest: Chemical and colloidal gels Model systems: i. LJ + FENE bonds (chemical gel), ii. DLVO (colloidal gel) Phenomenon: Dynamical heterogeneity Chemical gels: in the limit of large time mean cluster size of percolation. k dependence of yields percolation exponents. Colloids: given by the mean cluster size of mobile particles. Differences in the behavior of depending on definition (Fs(k,t) vs. overlap Q). Summary of results The asymptotic (t - infinity, k - 0) value of c4 gives the mean size of percolation clusters. cas(k) gives additional information about the structure of percolation clusters. In this case, dynamical heterogeneity is understood from geometry. Looking at dynamical heterogeneity offers a way of obtaining geometric information. What is new and interesting: Connection between dynamical heterogeneity and percolation Is dynamical heterogeneity that arises from structural heterogeneity interesting? In “attractive glasses”, gels etc, aspects of bonding and connectivity play a definite role, so has to be taken into account. Are there circumstances where looking at dynamical heterogeneity would be a relevant approach to getting information on structure? ? What is new and interesting: Connection between dynamical heterogeneity and percolation: Questions Description of dynamics in terms of the size dependent mobility of clusters. Useful in the case of transient clusters? What is new and interesting: Describing dynamics Qualitative dependence of dynamical susceptibility on definition via Fs(k,t) or overlap Q(t;a). Unlikely to affect results in high density glassy systems bu