KMnO4H2SO4引发制备淀粉改性絮凝剂的研究.PDFVIP

24 20 05 5 9 ENV IRONMENTAL CH EM ISTRY V o l. 24, N o. 5 September 2005 KM nO4 /H2 SO4 史俊杰 1 孙承林 1* 杨 旭 1 王 斌2 戴锡海 2 (1 , , 116023; 2 , , 113008 ) ,. . , KM nO4 ( 0 45mm o l l- 1 ) H2 SO4 ( 0 8mm o l l- 1 ) , 90% , , . ,, , , . , [ 1] lil [ 2 5] [ 6] , , , , , . . Rath . Kha . K arm akar . 1 11 ( 8% ) , 30m in, , , 50 350m l 8 10h, , ,. 12 250m l r m in- 1 , 0 25% 1m in, 60r m in- 1 2m in, . 13 GB /T 5009 5 2003 . PG ( % ) = GE (% ) = 0 15g, [ ], 100 / ( 2m o l l- 1 70 M ark H ouw ink[ 7] : = 0 66, M. . , , 85 , 3h. . 60 40( ) , 50 , , 5m in, 200 , UV 200 , 100 / +) , [ ] = KM , . , K = 3 73 10- 4, , FT IR ( EQU INOX55) 2005 1 30 *. . 566 24 2 21 1 , CO 22 3h) , . , ( , 90% , , 1010cm- 1, 1080cm - 1, 1150cm- 1 , 1615 cm- 1 1650cm- 1 [ 8] . CO NH2 , ( St) / H2 SO4 ( Am ) = 1 1( g /g ), KM nO 4 0 4mm o l l- 1, 60 , 2. H 2 SO 4 0 67 mm o l l- 1 , [ 9 ] : M nO2 + 2H + M n2+ + H 2 O + [ O ] , ,, , 0 8 mm o l l- 1 . 1 Fig 1 T he infrared spectrum o f St and St g Am 2 F ig 2 Effect of sulfuric ac id on grafting 23 3, ( S t/Am = 1 1( g / g) , H2 SO4 0 8mm o l l- 1, 60 , 3h) , , [ M n, ] 0 4 mm o l l- 1 , , , ,. [ M n, ] , [ M n, ] 0 45 mm o l l- 1 ,. ,, ,, . KM nO4 , M nO 2, pH 7 . , , , ., , ,, . 24 KM nO 4 0 45mm o l l- 1, H 2 SO4 0 8mm ol l- 1 , 60 3h, 4, , , ;, ., , , 0 8 1 2m ol l- 1 , , . 25 S t/Am = 1 1 ( g / g) , KM nO4 0 45mmo l l- 1, H 2 SO 4 0 8mm o l l- 1, , , 65 . 3 h, [ 10] 5 , ., ,, ,, . , 60 . 5 : KM nO4 /H2 SO4 56 7 3 F ig 3 E ffect o f [M n, ] on g rafting 4 Fig 4 Effect of [ Am ] on g ra fting 26 S t/Am = 1 1 ( g / g) , KM nO 4 0 45mm o l l- 1, H 2 SO4 0 8mm ol l- 1, A( / 15m in ), B ( ), C ( ) ( 6), A 10% . , ,, . 60 3h, ), D ( ( B), , 5 F ig 5 E ffect o f temperatu re on g ra fting 6 F ig 6 Effect of adding seguence on grafting 27 [ 9- 12] , St g Am1 , , : Vp = kp [M = k t [ M ] 2, [M ] , , , , ( 28 pH 2), . 6 , , , S t g Am2 150 . ] [M ], , , , : . . , , , St g Am 1 . Vt , 7 F ig 7 F loccu la ting effects of two co polym er izations on the kao lin sus