Al2O3聚砜复合超滤膜在大豆异黄酮中的提取研究+.pdfVIP

Al O －聚砜复合超滤膜在大豆异黄酮中的提取研究 2 3 * 张裕卿 , 涂郑禹，张红柳 （天津大学化工学院，天津 300072，中国） 摘 要：为了克服传统提取大豆异黄酮工艺中存在的耗能高、收率低、提取产品质量差等缺点，采用AlO － 2 3 聚砜复合膜为材料的超滤技术对粗大豆异黄酮料液进行精制，对影响超滤的主要工艺条件进行了考察。该提 取工艺过程中复合膜的最适截留分子量为10000，其提取过程在操作压力为0.1MPa~0.25MPa，温度为30℃， pH为5~6范围内得到大豆异黄酮的通量和收率较高。利用实验获得的最适宜操作条件，可使最终超滤后产品 中大豆异黄酮的质量分数达到30.23%。同时对该复合膜进行了清洗，洗涤后膜通量仍可达到原来的85%左右， 说明该复合膜在使用过程中具有一定的抗污染能力。 关键词：超滤；复合膜；聚砜；Al O ；大豆异黄酮；提取； 2 3 The Study on Extraction of Soybean Isoflavones with Alumina-Polysulfone Composite Ultrafiltration Membrane * ZHANG Yu-qing , TU Zheng-yu, ZHANG Hong-liu (School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China) Abstract: In order to conquer deficiencies of high energy、low yield and poor quality of product, this paper studied the purification of the soybean isoflavones’crude porduct with ultrafiltration technology which has Alumina-Polysulfone composite membrane as membrane-forming material. The primary conditions affecting ultrafiltration were also studied. The optimum extracting conditions were obtained as follow: membrane-forming material of 10000 MWCO, the temperature is 30℃, the pressure is 0.1MPa~0.25MPa, and pH is 5~6. Used optimum operational conditions in experiment, product contained 30.23% soybean isoflavones after ultrafiltration. After this composite membrane is cleaned, its flux also retain about 85% of beforetime, which means that it has anti-contamination ability in operation. Keywords: ultrafiltration; composite membrane; polysulfone; soybean isoflavones; extraction; 收稿日期：2006-08-20 作者简介：张裕卿，男，1963 年出生，生物化工专业博士后，副教授，研究生导师， (022)818