激光在制备生物陶瓷涂层中的应用.doc

激光技术制备生物陶瓷涂层的研究现状与展望 王迎春1 邓崎林2 李永祥1 耿铁1 吕翔飞1 (1河南工业大学机电工程学院,河南 郑州 450000; 2上海交通大学机械与动力学院，上海200030) 摘要：羟基磷灰石等生物陶瓷材料具有优良的生物相容性和生物活性，但其强度较低的力学性能限制了其广泛应用。在综合力学性能优良，生物活性有限的医用钛合金表面制备生物陶瓷涂层，能够扬长避短，充分发挥二者的优点，具有巨大的市场与应用价值，是国内外的研究热点。利用激光技术制备或改性生物陶瓷涂层，主要有以下几个领域的应用与研究：激光表面熔凝与其他涂层技术相结合；脉冲激光沉积法；激光熔覆等方法。本文全面阐述了国内外激光表面改性生物陶瓷涂层的研究现状与研究进展，并对其工艺与理论发展进行了展望。 关键词：激光; 表面改性; 脉冲激光沉积； 激光熔覆； 羟基磷灰石； 生物活性 ?中图分类号：TN249;TB;TG17 文献标识码 A Reviews of the Lasers technology fabrication of the bioceramic composite coatings Yingchun Wang1 Qilin Deng2 Yongxiang Li1 Tie Geng1 Xiangfei Lv1 1School of Mechanical and Electrical Engineering, Henan University of Technology, Zhengzhou, 450000, China 2School of Mechanical and Engineering, Shanghai Jiaotong University, Shanghai, 200030, China Abstract：The bioceramics such as hydroxyapatite and so on have excellent biocompatibility and bioactivity, but the mechanical properties with the low strength limited their wide applications. Fabrication of bioceramic coatings on biomedical titanium alloys with the excellent comprehensive mechanical strength and limited bioactivity can play their merits and overcome the shortcomings, which has the huge market and application value, and is the research hotspot in the world. For the laser technology fabricating or modifacting the bioceramic coatings, There are mainly some application and research areas as follows: The integration of the laser irradiation with other coatings fabrication technology; Pulsed laser deposition; laser cladding and so on. This paper reviews the status and development of the laser surface medication of the bioceramic coating in the world, and makes a prospect of the future of the technology and theory. Keywords: laser; surface modification; pulsed laser deposition; laser cladding; hydroxyapatite；bioactivity 1 引言 医用生物陶瓷是目前国内外正在蓬勃发展的生物材料，磷酸钙生物陶瓷是其中最有前途的骨替代材料 [1,2]。羟基磷灰石(HAP)，又称羟基磷灰钙，分子式Ca10(PO4)6(OH)2, 是磷酸钙生物陶瓷中的明星产品， 具有优良的生物相容性与生物活性，被认为是硬组织替代最合适的陶瓷材料。但强度低，韧性差的力学性能限制了其广泛应用[3,4