An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode Three-dimensional porous graphene-mesoporous platinum nanoparticle composite.pdfVIP
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An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode Three-dimensional porous graphene-mesoporous platinum nanoparticle composite.pdf
Sensors and Actuators B 239 (2017) 438–446
Contents lists available at ScienceDirect
Sensors and Actuators B: Chemical
journal homepage: /locate/snb
An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite
Jinghui Li a,b, Tanji Yin a,?, Wei Qin a,?
a Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research (YIC), Chinese Academy of Sciences (CAS), Shandong Provincial Key Laboratory of Coastal Environmental Processes, YICCAS, Yantai, Shandong 264003, PR China b University of the Chinese Academy of Sciences, Beijing 100049, PR China
article info
Article history: Received 21 June 2016 Received in revised form 30 July 2016 Accepted 1 August 2016 Available online 2 August 2016
Keywords: Three-dimensional porous graphene Mesoporous platinum nanoparticles Solid contact All-solid-state ion-selective electrode Cadmium
abstract
The three-dimensional porous graphene-mesoporous platinum nanoparticle (3D PGR-MPN) composite is used as solid contact for developing an all-solid-state polymeric membrane Cd2+ ion-selective electrode (Cd2+-ISE). The 3D PGR with MPNs as cross-linking sites can be synthesized by a facile hydrothermal coassembly method. The obtained 3D PGR-MPN composite is promising for acting as solid contact due to its unique characteristics such as high interfacial area, superior double layer capacitance, excellent conductivity and high hydrophobicity. The ISE exhibits a stable Nernstian response in the range of 10?8–10?4 M and the detection limit is 10?8.8 M. The 3D PGR-MPN-based Cd2+-ISE shows good potential response and no water layer exists between the polymeric membrane and the 3D PGR-MPN layer. Additionally, the proposed Cd2+-ISE is robust to O2, CO2 and light interferences. This work provides a versatile method for preparing an effective solid contact to develop a stable and reliable al
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