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Possible origins of superconductivity in PrBa2Cu3Ox compound viewed from results of single crystal structure study.pdf

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Possible origins of superconductivity in PrBa2Cu3Ox compound viewed from results of single crystal structure study.pdf

Journal of Alloys and Compounds 288 (1999) 319–325 L Possible origins of superconductivity in PrBa2Cu3Ox compound viewed from results of single crystal structure study Jinhua Yea ,*, Zhigang Zoub, Kunihiko Okab, Yoshikazu Nishiharab,c, Takehiko Matsumotoa aNational Research Institute for Metals, 1-2-1 Sengen, Tsukuba, Ibaraki, Japan bElectrotechnical Laboratory, 1-1-4 Umezono, Tsukuba, Ibaraki 305, Japan cFaculty of Science, Ibaraki University, Bunkyo 2-2-1, Mito 310, Japan Received 1 February 1999; received in revised form 27 February 1999 Abstract Structural differences of the superconducting PrBa2Cu3Ox crystals grown by the TSFZ method and the semiconducting ?ux grown crystals were investigated using X-ray diffraction method. The TSFZ grown crystals tend to have a longer c-axis length than the ?ux grown crystals, in both of the as-grown and oxygen-annealed crystals. Precise structure re?nement revealed that the longer c-axis length in the as-grown tetragonal TSFZ crystals is attributed to the expansion of distance between the two CuO2 planes. The Pr–O(2) bond length, however, does not show elongation. The most signi?cant differences between the structures of the TSFZ and the ?ux crystals are found to be the occupancy parameter of the Cu(1) site and the thermal displacement parameter of the apical O(4) atom, implying a close relation of these structural parameters to the different electronic properties of the two crystals. ? 1999 Elsevier Science S.A. All rights reserved. Keywords: PrBa2Cu3Ox; Crystal structure; Superconductivity 1. Introduction PrBa2Cu3Ox (Pr123), a compound being extensively investigated [1–7] for its unique behavior to be nonsuperconducting among the high-Tc RBa2Cu3Ox (R123) cuprates, is now attracting a wide audience again for the newly identi?ed superconductivity. Early in 1996, Blackstead et al. have reported an inhomogeneous superconductivity in a ?ne PrBa2Cu3Ox ?lm [8]. Zou et al.’s success in growing superconducting PrBa2Cu3Ox single crys