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Preparation of organic–inorganic hybrid silica nanoparticles with contact antibacterial properties and their application in UV-curable coatings.pdf

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Preparation of organic–inorganic hybrid silica nanoparticles with contact antibacterial properties and their application in UV-curable coatings.pdf

Progress in Organic Coatings 106 (2017) 20–26 Contents lists available at ScienceDirect Progress in Organic Coatings journal homepage: /locate/porgcoat Preparation of organic–inorganic hybrid silica nanoparticles with contact antibacterial properties and their application in UV-curable coatings Huiwen Ge, Jinfeng Zhang, Yan Yuan, Jingcheng Liu, Ren Liu ?, Xiaoya Liu The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China article info Article history: Received 5 May 2016 Received in revised form 3 January 2017 Accepted 13 February 2017 Keywords: UV-curable coating Organic–inorganic hybrid nanoparticle Quaternary ammonium compound Contact antibacterial property abstract With the increasing requirements of antibacterial in various ?elds, it is necessary to create ultraviolet (UV)-curable coating with antibacterial properties by adding antibacterial agents to coating formulations. Therefore, it is crucial to promote the development of coatings designed with UV-curable addition agents that possess excellent antibacterial activity and suitable mechanical properties. In this study, a series of silica nanoparticles was developed with photo-cross-linking and antibacterial properties. The effects of various grafting ratios of photosensitive groups and antimicrobial function groups on the dispersity and antibacterial performance of nanoparticles were evaluated. The ?ndings indicate that nanoparticles modi?ed with quaternary ammonium species possess good dispersity and antibacterial ability. The series of functional silica nanoparticles, which act as organic–inorganic hybrid UV-curable antibacterial agents, was added to soybean oil-based UV-curable coating formulations. The basic coating properties of different species of nanoparticles were systematically investigated. Antibacterial tests of coatings were also conducted. With a proper grafting ratio of antimicrobial functi