微絮凝用于化工废水回用中反渗透预处理的试验研究.pdfVIP

第五届全国化学工程与生物化工年会 - 14 ．绿色化学工程与工艺 微絮凝用于化工废水回用中反渗透预处理 的试验研究 任松洁，张继伟，吴伟勇，许炉生，张国亮* （浙江工业大学生物与环境工程学院，浙江杭州 310014） 摘要: 在反渗透操作之前采用微絮凝处理工艺，可以有效去除DOP 化工废水二级生化池出水中的悬浮颗粒 物和有机物，以减轻深度处理工艺中反渗透膜的污染。试验考察了不同pH 和不同浓度PAC 条件下微絮凝对 废水中COD 去除的效果，实验结果显示pH=8、PAC 投加量为750 mg ·L-1 时，COD 的去除效果可达34.32%， 废水浊度也由原来的 25.1 NTU 下降到 7.5 NTU。对微絮凝-反渗透工艺运行中各项参数的检测分析表明， 微絮凝作为反渗透的预处理工艺,不仅可以使系统运行稳定,而且相对于目前工业上普遍使用的全膜法工艺, 投资和运行费用相对较低,具有良好的推广应用价值。 关键词：化工废水；回用；微絮凝；反渗透；预处理 Micro-coagulation used as pretreatment of reverse osmosis membrane process in chemical wastewater reutilization * REN Songjie, ZHANG Jiwei ，WU Weiyong, XU Lusheng, ZHANG Guoliang (College of Biological Environmental Engineering, Zhejiang University of Technology, HangZhou 310014, China) Abstract ：Micro- coagulation was used as pretreatment of reverse osmosis membrane process in advanced treatment of secondary effluent from dioctyl phthalate (DOP) chemical plant for reutilization. The wastewater from chemical DOP production treated by micro-coagulation after anaerobic and aerobic processes contained so fewer solid wastes and organics that membrane fouling could be prevented effectively. The optimum was 34.32% and the turbidity of wastewater was cut down from 25.1 to 7.5 NTU at pH 8 and 750 mg/L dose of polyaluminium chloride (PAC). All these results showed performance of RO membranes coupling with micro-coagulation in wastewater treatment held better stabilization of flux and rejecting ability than the others commonly used in practical waste treatment. Key words: micro-coagulation; pretreatment; reverse osmosis; wastewater reuse 前言 前景相当广阔。但是，由于长时间的运行， 随着现代化工行业的日益发展，其用水 悬浮物和颗粒物在膜表面以及在膜内部的 量及废水排