洁净柴油用新型加氢脱硫催化剂活性位的设计.pdf

洁净柴油用新型加氢脱硫催化剂活性位的设计 11 1 1 1 2 陶克毅 李 伟 张明慧 李国然 牟诗诚 （1．南开大学化学学院，天津300071，中国；2.国家纳米技术与工程研究院，天津300457，中国） 摘要：随着世界经济的发展，市场对燃油的需求量迅速增加，同时日益严格的环保标准要求质量更高的 清洁燃油。油品中硫含量的控制是当前各国清洁燃料生产的核心。工业上主要通过加氢脱硫（HDS ）技术提 高油品的质量，而HDS 催化剂（通常是硫化物 Co(Ni)Mo(W)/Al2O3 ）则是此技术的关键。作为提高催化剂性 能的重要途径，本文在纳米尺度内探究催化剂活性位微观结构与催化活性间的关系，并应用新方法使作为制 备出活性位具有特定结构的催化剂: 纳米尺度的 MoS2 选择性的沉积到 Co(Ni)的纳米粒子上。所制催化剂在二 苯并噻吩（DBT ）的HDS 反应中表现出了高于传统催化剂的活性。这些实验结果对开发高性能 HDS 催化剂 和清洁燃油的生产具有重要的实用价值和理论意义。 关键词：洁净柴油，加氢脱硫；催化剂；活性位；设计 Design of Catalytic Active Sites of Novel Hydrodesulfurization Catalysts for Clean Diesel Fuel 1 1 1 1 2 TAO Ke-yi , LI Wei , ZHANG Ming-hui , LI Guo-ran , MU Shi-cheng (1.College of Nankai University, Tianjin 300071,China; 2.China National Academy of Nanotechnology Engineering Tianjin 300457,China) Abstract: Hydrodesulfurization (HDS) catalysis is an indispensable process for producing clean fuel. Alumina-supported catalysts based on sulfided molybdenum promoted by Co or Ni are commonly used as HDS catalysts in the petroleum industry Recently, increasing environmental pressures and economical reasons have pointed out the necessity to develop new hydrotreating catalysts with enhanced properties. To enhance catalytic activity, a novel model of HDS active site is proposed: metallic Co(Ni) is supported on the surface of supports and active component MoS2 is dispersed on the surface of metallic Co(Ni) particles, and there is a certain interaction between Co(Ni) and MoS . An induction deposition method has been developed to prepare the new 2 catalysts with the designed structure. A mixed aqueous solution of (NH ) Mo O ·4H O