高度な難燃性能を有する木質系防火材料の開発（第1報）.pdfVIP

1 Development of Wood-Based Material with High Fire Preventive Performance (I) - Investigation of fire retardants mixed with adhesives - Masayuki KAWARASAKI Ryouichi HIRADATE Shinichi KIKUCHI Yasushi HIRABAYASHI Some fire retardants mixed with an adhesive were examined for their influence on fire preventive of plywood. The retardants were selected based on their fire preventive effect, bond strength and formaldehyde emission. These of an intumescent type were composed of a catalyst, a carbonific material and a blowing agent. All fire retardants tested were effective for fire preventive of plywood, and the following agents were suitable. Adhesive: Melamin resin adhesive. Fire retardant: Ammonium polyphosphate as the catalyst, pentaerithritol as the carbonific material, and dicyanodiamide or azodicarbonamide as the blowing agent. Key words: plywood, fire preventive, adhesive, fire retardant, intumescent type 3 J. Hokkaido For. Prod. Res. Inst. Vol.18, No.4, 2004 1. 10 ISO 5660 2-4 1 5-8) 2.1 US-6200 2. UF U-355 MF 2 1 Table 1. Ingredients of fire retardant. Ingredient Sy mbol Comp ound APP Ammonium polyphosphate Cat aly st GUP Guanylurea phosphate DGP Diguanidine phosphate PER Carbonific material Pent aery t hrit ol Blowing agent DIC Dicy anodiamide AZO Azodicarbonamide 2 Table 2. Combinations of fire retardant ingredients. Fire retardant AD AA GD GA DD DA Cat aly st APP GUP DGP Carbonific material PER Blowing agent DIC AZO DIC AZO DIC AZO =100 5 1 2.2 94 94mm 3 1 2 3 1 =6 2 1 =100 45 5 1 2 ISO 5657 2.2.1 0.40 0.50 165 165 9mm 5 3 390g/m2 5 2.2.2 ISO 40kW/m2 115 40 3 48 24 140mm 6 4 LB-080 5 LB-1100 1 Aluminium foil 50mm 50mm 50mm 50mm Exposure area Specimen Baseboard 140mm 2.3 2.3.1 1 300mm 3 3.6mm 0.5 6.0 0.4 2.1 0.57 440g/m2 980kPa 790kPa 3 2.3.2 30 1.3mm 0.05 6.3 0.51 0.05 100 15 1 115 JAS 2 2 JAS 14 20 B 28 65 R.H. 1 AUTOGRAPH S-500 1.0mm/min 2.3.3 JAS 32 R.H. 10 1 150 50mm 1 10 20 65 1 3 140mm Cross section 1 Fig.1. Measuring points of height of insulating foam.