球磨環境对La2Mg750wt%Ni合金储氢能影响研究本科毕业专业论文.docxVIP

内蒙古科技大学 本科生毕业论文 题目： 球磨环境对La2Mg17+50wt.%Ni合金储氢性能影响研究 学生姓名：冯家琪 学 号：1077145115 专 业：稀土工程 班 级：10级1班 指导教师：李霞 讲师 球磨环境对La2Mg17+50wt.%Ni合金储氢性能影响研究 摘 要 镁基贮氢合金中的La2Mg17受关注的程度比较高，同时具有很好的开发前景，这主要是基于其价格比较低，同时理论电化学容量很高。 本文通过研究不同球磨环境（是研究在氩气保护下添加有机溶剂环己烷、苯、丙酮）下，对La2Mg17+50wt.%Ni复合合金相结构、吸氢性能的影响，发现，XRD结果表明在氩气保护下苯、环己烷、丙酮中球磨20h的La2Mg17+50wt.%复合合金的衍射峰半峰宽和相对峰强度比氩气保护下球磨的均变宽和变弱。300℃温度下，吸氢速率曲线表明环己烷球磨改性的La2Mg17+50wt.%复合合金表现出最好的活化性能，最大吸氢量为2.845 wt.%。 经研究发现加有机溶剂在氩气保护下球磨后，可以改善La2Mg17的储氢动力学性能，提高储氢量。在进行球磨时，因为存在有机溶剂，当粉末颗粒的表面张力想要增加时，有机溶剂就会起到抑制作用，这样颗粒就比较小了。另外，因为存在能量很高的磨球的撞击，这时就使得试样颗粒内部存在很多严重的缺陷，直接使自由能变大，颗粒的表面张力就是这种情况。从而使得吸氢量变大。 关键词： La2Mg17、球磨、储氢性能、非晶态 Effect of different milling environment on hydrogen storage properties of La2Mg17 +50 wt.% Ni alloy Abstract Magnesium-based hydrogen storage alloys La2Mg17 because of its advantage of high electrochemical capacity and low price，attracted widespread attention and is considered an important development prospects. By studying different milling environments (adding an organic solvent to study cyclohexane, benzene, acetone under argon), the right La2Mg17+50 wt. %Ni alloy phase composite structure, hydrogen absorption properties, find, XRD results showed under argon, benzene, cyclohexane, acetone, and the diffraction peak half-width of the peak intensities milling La2Mg17 +50 wt.% Ni of the composite alloy 20h under argon than are widened and milling becomes weaker. Temperature of 300℃, hydrogen absorption rate curve showed cyclohexane milling modified La2Mg17+50wt.%Ni Composite alloy exhibits the best performance activated, the maximum hydrogen absorption capacity of 2.845 wt.%. The study found that the addition of an organic solvent under an argon atmosphere in a ball mill,to improve the dynamic performance of hydrogen storage La2Mg17 improve the hydrogen storage capacity. In the milling process，the organic solvent is suppressed to some extent to increase the surface tension of the powder particles， the particles can exist in a smaller size