纤维素可控接枝聚合技术的研究进展.pdfVIP

I专题论坛 一．一——————————————————————————————————————————————————————————————————————_——————————————————————————————·—————————————————————————，—’————————‘—————————————————‘——一 ·接枝聚合’ 作者简介：李德娟女士， 在读硕士研究生；研究 方向：纤维资源的制浆 造纸特性与生物技术。 纤维素可控接枝聚合技术的研究进展 李德娟 傅英娟+ 秦梦华 (齐鲁工业大学制浆造纸科学与技术省部共建教育部重点实验室，山东济南，250353) 摘要：介绍了近年来纤维素及其衍生物接枝聚合技术的研究进展及应用，重点介绍了新型的活性- 可控自由基接枝聚合技术，包括氮氧稳定自由基聚合(NMP)、原子转移自由基聚合(ATRP)和可 逆加成一断裂链转移自由基聚合(RAFT)，主要阐述了聚合机理、优缺点和自在纤维素及其衍生物可 控接枝聚合改性方面的应用。 关键词：纤维素；活性一可控自由基接枝聚合技术；氮氧稳定自由基聚合；原子转移自由基聚合；可 逆加成-断裂链转移自由基聚合 中图分类号：TS71+．2 文献标识码：A 文章编号：0254-508X(2013)07一0060-07 Research Progress of Cellulose Controlled Graft Copolymerization Technology LI De-juan FU Ying-juan+ QIN Meng—hua (Key Lab of n咖Paper Science and Technology of Ministry of Education，Qilu University of Technology， 五’nan，Shandong Province，250353) ($E—mail：fyingjuan@163．corn) Abstract：Cellulose，the most abundant natural polymer，is a kind of renewable and inexhaustible sonrce in the world．Designing the chemi- cal structure of ceHulose to creat special functional material is an important way to expand the apphcation area of cellulose．In this paper，the research advance and application of cellulose and cellulose derivatives graft copolymerization technology were reviewed．Cellulose graft copol— ymerization technology mainly includes the traditional graft copolymerization and new type of active／controlled radical graft copolymerization technology．This paper emphasizes on the active／controlled radical graft copolymerization technology such as NMP、ATRP and RAFr—tech- nology，including their mechanism，corresponding advantages and application in cellulose and ceHulose derivatives controlled graft copoly— merization． Key words：cellulose；active／controlled radical graft polymerization technology；nitroxide—mediated stable free—radical polymerization (NMP)；atom transfer radical polymerization(ATRP)；reversible addition-fragmentation chain transfer polymerization(RAFr) 随着石油、天然气等不可再生资源的日渐枯竭， 石油价格的飞速增长，以及石油化工产品所引起的环 境污染日益加重，天然可再生资源的开发和高值化利