食品包裝材料中油墨成分的迁移及溶出毕业专业论文.docVIP

食品包装材料中油墨成分的迁移及溶出 摘　　要 用固相微萃取-气相色谱质谱联用技术（SPME/GC-MS）液用固相微萃取（SPME）技术进行萃取，对萃取头、萃取温度时间进行了优化。利用GC-MS对目标物进行定量分析。结果表明，二苯甲酮和4-甲基二苯甲酮在0.03μg/L～1.0μg/L的范围内线性关系均良好（r2≥0.99），检测限分别为0.0012μg/L、0.0040μg/L。两种目标物在添加水平下，平均回收率为75.1%～95.6%，相对标准偏差均小于11.5%。本方法简单、快速、准确，能够满足食品包装的日常检验需要。 关键词：包装材料；气相色谱质谱法；光引发剂 Migration and dissolution of components in printing ink of food packing materials ABSTRACT Food stimulant and solid phase microextractiongas chromatography-mass spectrometry (SPME/GC-MS) were used in the abstraction experiment. A method for the determination of two kind of photoinitiators migrated from the printing ink on the surface of food packaging material has been developed. Photoinitiators in the food packaging samples were abstracted with food stimulant at the condition of 4℃、45℃、120min. The influence of temperature and time were for photoinitiators’ abstraction was studyed. Abstract was extracted by a solid phase microextraction （SPME）technology. Extraction, temperature and time were optimized. The target was analysised by GC-MS. The results showed that, the limit of detection for benzophenone and 4-methyl benzophenone was 0.0012μg/L and 0.0040μg/L with a good linear correlation (r2≥0.99) in the range of 0.03μg/L～1.0μg/L.The average recoveries of the two compounds at spiked level of were 75.1%～95.6%, with the relative standard deviation were less than 11.5%. The method was simple, rapid, accurate and can satisfy the daily inspection of food packaging. Keywords:ackaging material；Food stimulant ；Gas chromatography-mass spectrometry；Photoinitiatorbstraction experiment 目　　录1　前言 1 1.1　食品安全问题 1 1.2　油墨中的光引发剂 1 1.3　食品模拟物 1 1.4　国内外对光引发剂迁移的研究 2 1.5　本实验研究内容及意义 3 2　实验部分 4 2.1　仪器与试剂 4 2.2　实验样品 4 2.3　标准溶液 4 2.4　实验方法 4 2.4.1　样品前处理 4 2.4.2　实验条件 4 3　结果与讨论 6 3.1　光引发剂萃取条件的确定 6 3.1.1　萃取头的选择 6 3.1.2　萃取温度和时间的选择 6 3.2　光引发剂迁移实验 7 3.2.1　迁移温度的选择 7 3.2.2　不同食品模拟物的迁移 8 3.3　方法评价 8 3.4　实际样品的测定 9 4　结论 11 参考文献 12 致谢 13 附录 14 1　　前言 1.1　食品安全问题 食品安全关系着人们身体健康和生命安全、经济健康发展、社会发展与稳定。包装材料能保护食品免于外来因素的损害，对食品质