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桃園創新學報 第三十三期 鉬改質酚醛樹脂/氮化鋁陶瓷複合材料的製備及其性質研究 95 PREPARATION AND PROPERTIES OF MOLYBDENUM MODIFIED PHENOLIC RESIN/ALUMINUM NITRIDE COMPOSITES Chun-Te Lin 1，Hsun-Tsing Lee 2，Pin-Ho Lin3* 1，3* Department of Applied Cosmetology, Taoyuan Innovation Institute of Technology, Chung-Li, Tao-Yuan 2 Nanomaterials application RD center, Vanung University, Chung-Li, Tao-Yuan Abstract Novolac-type bisphenol-F based molybdenum-phenolic resins/silane-modified aluminum nitride (Mo-BPF/m-AlN) composites were successfully prepared. In the preparation process, molybdate reacted with bisphenol-F based phenolic resins (BPF) to form a low cross-linked Mo-BPF with new Mo-O bonds. Simultaneously, a special silane-modified aluminum nitride (m-AlN) was prepared. Then, this m-AlN was fully mixed with Mo-BPF to form Mo-BPF/m-AlN. The structure and characterization of BPF, Mo-BPF and Mo-BPF/m-AlN were determined by using FTIR, DSC, DMA, TGA and SEM. The glass transition temperature, thermal resistance, flexural strength, and hardness of Mo-BPF are respectively higher than those of BPF. When the m-AlN was additionally incorporated into Mo-BPF, the well-dispersed and well-adhered m-AlN can further promote all the above-mentioned properties of the composites. Typically, the glass transition temperature, decomposition temperature at 5% weight loss and flexural strength of Mo-BPF/m-AlN are 245 o C, 428 o C and 82.7 MPa respectively, which are much higher than the corresponding values of 184 o C, 358 o C and 58.2 MPa for BPF. Keywords：Molybdenum-phenolic resin, Bisphenol-F, Aluminum nitride, Ammonium molybdate *Email：lin101@tiit.edu.tw TEL:03-4361070 ext 2301 桃園創新學報 第三十三期 鉬改質酚醛樹脂/氮化鋁陶瓷複合材料的製備及其性質研究 96 鉬改質酚醛樹脂/氮化鋁陶瓷複合材料的製備及 其性質研究 林俊德 1、李訓清 2、林平和 3* 桃園創新技術學院化妝品應用系 1，3* 萬能科技大學奈米材料應用研發中心 2 摘要 本試驗成功製備出的鉬改質酚醛樹脂/氮化鋁複合材料（Mo-BPF/m-AlN），在 製備過程中鉬酸鹽與酚醛樹脂（BPF）反應後形成具有 Mo-O 鍵結的低交聯度鉬酚 醛樹脂（Mo-BPF），同時也製備出 APTES 表面處理的氮化鋁陶瓷材料（m-AlN）， 然後 m-AlN 與 Mo-BPF 混合後形成 Mo-BPF/m-AlN 複合材