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calcium hydroxyapatite modified with metal ions.pdf

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calcium hydroxyapatite modified with metal ions

Colloids and Surfaces A: Physicochemical and Engineering Aspects 142 (1998) 107–116 Surface composition of calcium hydroxyapatite modified with metal ions Masato Wakamura, Kazuhiko Kandori, Tatsuo Ishikawa * School of Chemistry, Osaka University of Education, 4-698-1 Asahigaoka, Kashiwara-shi, Osaka 582-8582, Japan Received 14 January 1998; accepted 21 April 1998 Abstract Colloidal calcium hydroxyapatite (CaHAP) particles were modified with Ni2+, Cu2+, Co2+ and Cr3+ ions by ion- exchange and coprecipitation. The CaHAPs doped with these ions were characterized by various methods including FTIR, XPS, TEM and ICP. The atomic ratio, metal/(Ca+metal ), of the surface phase (Xs) of the particles modified with Ni2+ and Cu2+ by coprecipitation was much less than the atomic ratio of the whole particle (Xw), while Xs of the particles modified with Cr3+ approximated to their Xw. In the modification by ion-exchange, Xs was larger than Xw except for the Ni2+-substituted samples where Xs was identical to Xw. The surface P–OH groups were decreased by cation-exchange of the protons of the P–OH groups with Ni2+, Cu2+ and Co2+ in both the modification methods. On the other hand, Cr3+ ions were doped in the surface phase by anion-exchange of the surface phosphate ions with hydrated chromium hydroxide anions. ? 1998 Elsevier Science B.V. All rights reserved. Keywords: Calcium hydroxyapatite; FTIR; Ion-exchange; Surface modification; XPS 1. Introduction CaHAP can be anticipated to be altered by ion- exchange of Ca2+ with metal ions. It has been Calcium hydroxyapatite, Ca10(PO4)6(OH )2, reported that Cu2+, Ni2+ and Pb2+ doped into abbreviated as CaHAP, is not only a main compo- CaHAP influence the catalytic activity of this nent of hard tissues, such as bones and teeth, but material [10,11]. Nevertheless, the surface struc- also a material applied for bioceramics, adsorbents ture of the metal-substituted CaHAP is poorly and catalysts. The surface structure and properties understood. Info