基于纳米压痕试验的混凝土微观耐久性表征.pdf

第36卷 第1期 力 学 季 刊 Vol.36 No.1 2015年3月 CHINESE QUARTERLY OF MECHANICS March 2015 doi: 10.15959/j.cnki.0254-0053.2015.01.010 收稿日期： 2015-01-05 基金项目： 作者简介： 国家自然科学基金 陈仁宏(1989?)，男，湖南常德人，硕士生．研究方向：材料力学性能表征． 通信作者： 乔丕忠．Email: qiao@sjtu.edu.cn 基于纳米压痕试验的混凝土微观耐久性表征 陈仁宏 1 ，乔丕忠 1,2 (1．上海交通大学 工程力学系，上海 200240；2．上海交通大学 海洋工程国家重点实验室，上海 200240) 摘要：利用纳米压痕和扫描电镜研究了不同冻融循环下混凝土的微观性能，揭示了冻融循环所导致混凝土退化 的机理．纳米压痕结果显示，混凝土浆体的压痕模量与硬度的相关系数很大，并且都不满足正态分布．本文利 用核密度估计来计算浆体微观性能的概率密度函数．根据浆体和骨料的性能差异，用阶跃函数来拟合界面过渡 区的微观力学性能，同时利用扫描电镜观察界面过渡区的形貌．采用以上两种方法研究不同冻融循环下的混凝 土，发现在不同的尺度下，冻融循环对混凝土的影响不同：在纳米尺度下，由于水的参与，高密度水凝胶会进 一步形成；而在微米尺度下，由于冻融循环中水结冰膨胀和材料多相性，微裂纹进一步扩展，导致断裂能量降 低，混凝土表现出宏观退化． 关键词：纳米压痕；冻融循环；混凝土耐久性；退化机理 中图分类号：O348.3 文献标志码：A 文章编号：0254-0053(2015)01-0088-07 Microscopic Characterization of Concrete Durability Using Nano-Indentation Tests CHEN Ren-hong1, QIAO Pi-zhong1,2 (1. Department of Engineering Mechanics, Shanghai Jiao Tong University, Shanghai 200240, China; 2. State Key Laboratory of Ocean Engineering, Shanghai Jiao Tong University, Shanghai 200240, China) Abstract: Nano-indentation and scanning electron microscopy (SEM) were used to reveal the intrinsic microscopic properties of concrete and deterioration mechanism of concrete due to cyclic freezing/thawing (F/T) damage. Characterization results on the 0 F/T cycle mortar indicates that, the hardness and indentation modulus are highly correlated by Pearsons correlation coefficient and their histograms fail to comply with the normal distribution. The kernel density estimation was utilized to provide a global distribution function instead of several Gaussian curve additions. The nanoscale mechanical properties at the neighbor of interfacial transition zone (ITZ) were approximated by Heaviside function, and a procedure for determining ITZ was made by considering the difference of mechanical properties. Studying different F/T degradation samples indicates that, the multi-scale nature of concrete leads to material degradation