Effects of iron surface pretreatment on kinetics of.pdfVIP

下载本文档

2
0
约2.16万字
约 6页
2017-04-09 发布于江苏
举报
版权申诉

Effects of iron surface pretreatment on kinetics of.pdf

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Effects of iron surface pretreatment on kinetics of

Journal of Hazardous Materials B126 (2005) 189–194 Effects of iron surface pretreatment on kinetics of aqueous nitrate reduction Ya Hsuan Liou a,? , Shang-Lien Lo a , Chin-Jung Lin a , Wen Hui Kuan b , Shih Chi Weng a a Research Center for Environmental Pollution Prevention and Control Technology, Graduate Institute of Environmental Engineering, National Taiwan University, Taipei 106, Taiwan, ROC b Department of Environmental and Safety Engineering, Ming-Chi Institute of Technology, Taishan, Taipei hsien 243, Taiwan, ROC Received 8 April 2005; accepted 27 June 2005 Available online 10 August 2005 Abstract Using hydrogen gas at 400 ? C to activate iron surface was proposed to remove nitrate (40 mg N L ?1 ) in a HEPES buffer solution at pH value between 6.5 and 7.5. Compared with the nonpretreated iron, the first-order reaction rate constant (kobs) was increased 4.7 times by p w f r c ( i a ? K 1 t [ t a d t c F p i 0 dretreated iron, and the lag of the early period disappeared. Normalized to iron surface area concentration, the specific rate constant (kSA) as increased approximately by a factor of 6 using hydrogen reduction (0.0020 min ?1 m ?2 L for nonpretreated iron and 0.0128 min ?1 m ?2 L or pretreated iron). The reactivity of aged iron covered by a complex mixture of iron oxides (soaking in nitrate solution for 60 days) were estored by hydrogen gas at 400 ? C. Scanning electron microscopy (SEM) and temperature-programmed reduction (TPR) exhibited visibly leaner without pitting and cracking and less oxygen fraction on pretreated iron surface relative to nonpretreated iron. Activation energies Ea) of nitrate reduction over the temperature range of 10–45 ?C were 46.0 kJ mol?1 for nonpretreated iron, and 32.0 kJ mol?1 for pretreated ron, indicating chemical reaction control, rather than diffusion. The results indicated that this enhancement was attributed to the increase in ctive site concentration on iron surface by hydrogen reduction. 2005 Elsevier B.V. All rights