ZSM-12 分子筛研究进展.pdf

2007年第 26卷第 7期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·921· 化 工 进 展 ZSM-12分子筛研究进展 吴 伟 1，2 ，黄 娟 2 ，吴维果 2 ( 1 哈尔滨工程大学材料科学与化工学院，黑龙江 哈尔滨 150001； 2 黑龙江大学化学化工与材料学院， 黑龙江 哈尔滨 150080 ) 摘 要：综述了水热合成法制备 ZSM-12分子筛的影响因素、改性方法及其在催化反应中的应用。众多研究表明， 模板剂种类影响 ZSM-12 分子筛晶粒的尺寸、形状以及酸性，硅铝比和碱度是影响 ZSM-12 分子筛合成的主要因 素，硅凝胶是合成 ZSM-12的适宜硅源。Ga、Fe 、B、P等适宜的杂原子对 ZSM-12进行同晶置换改性可以调节 其酸性，酸脱铝改性可以使其总酸量减少、Lewis酸消失。ZSM-12可作为芳烃烷基化、异构化、裂化、重整等诸 多反应的催化剂，在反应中表现出良好的催化活性及对目标产物的高选择性，是目前用于择形催化一步法合成 2,6- 二甲基萘最适宜的分子筛催化剂。 关键词：ZSM-12分子筛; 改性; 表征; 催化; 2,6-二甲基萘 中图分类号：TQ 426 文献标识码：A 文章编号：1000–6613（2007）07–0921–06 Research progress of ZSM-12 molecular sieve WU Wei 1,2 ，HUANG Juan 2 ，WU Weiguo 2 ( 1 School of Materials Sciences and Chemical Engineering，Harbin Engineering University，Harbin 150001， Heilongjiang，China； 2 School of Chemistry and Material Sciences，Heilongjiang University，Harbin 150080， Heilongjiang，China) Abstract：The factors affecting the hydrothermal synthesis of molecular sieves with ZSM-12 structure， modification methods as well as application in catalysis are reviewed. A lot of studies show that alkalinity and Si/Al ratio in initial reactive gel are major factors during the synthesis of ZSM-12. Different templates can considerably affect pore dimension，crystal morphology and acidity. Silica gel is the suitable source of silicate. Isomorphic substitution of atoms of crystal framework of ZSM-12 with Ga，Fe，B and P compounds can adjust its acidity. The total amount of acid sites decreases while Lewis acid sites disappear during dealumination of ZSM-12. The catalysts based on ZSM-12 show better catalytic activity and high selectivity in aromatic alkylation，isomerization，cracking，and reforming. It is considered to be the best catalyst for preparing 2,6-dimethylnaphthalene by the shape-selective catalysis one-step method. Key words：ZSM-12 molecular sieve; modification; characterization; catalysis; 2,6-dimethylnaphthalene 沸石分子筛具有规则均匀的孔道结构、良好的 稳定性和