AppliedThermodynamics應用热力学.pptVIP

Applied Thermodynamics應用熱力學 Chapter I Introduction 化學工業程序 混合、分離；操作狀態條件的控制 化學工廠常見的分離操作程序 蒸餾 → 氣液平衡、氣液液平衡 萃取 → 液液平衡 吸收 → 氣液平衡 結晶 → 固液平衡 吸附 → 吸附相與流體相之平衡 超臨界萃取 → 氣液平衡、氣固平衡 Chapter 1 Introduction 流體熱物性與工程上之相關性 儲槽設計 → 密度、飽和壓力 蒸餾塔模擬與設計→ 氣液平衡、熱焓 程序效率分析與最適化計算→ 熱焓、熵 煤液化程序設計→ 密度、蒸氣壓、熱焓、氣液平衡、固液平衡、化學反應平衡、黏度、熱傳導度、擴散係數 Chapter 1 Introduction 哈伯程序 魯奇煤的氣化程序 Fischer - Tropsch 程序 Chapter 1 Introduction 煤的氣化與重要衍生程序 Chapter 1 Introduction History of human 1914 ~ 1918 (War I) 1939 ~ 1945 (War II) Oh ! Human ! Ya ! Human ! Haber – Bosch Process Fritz Haber (left, 1.0 Nobel prizes in 1918) and Carl Bosch (right, 0.5 Nobels in 1931) have probably had a greater impact than anyone in the past 100 years, including Hitler, Gandhi, Einstein, etc. Their Haber-Bosch process has often been called the most important invention of the 20th century (e.g., V. Smil, Nature, July 29 1999, p 415) as it detonated the population explosion, driving the worlds population from 1.6 billion in 1900 to 6 billion in 2000. Haber – Bosch Process History (from Google) Since the invention of the original process by the German researchers Franz Fischer and Hans Tropsch, working at the Kaiser Wilhelm Institute in the 1920s, many refinements and adjustments have been made, and the term Fischer-Tropsch now applies to a wide variety of similar processes (Fischer-Tropsch synthesis or Fischer-Tropsch chemistry). Fischer and Tropsch filed a number of patents, e.g. US patent no. 1,746,464, applied 1926, published 1930 [4].  Fischer-Tropsch Process Coal Lurgi coal gasification ? Synthesis gas Synthesis gas ? Methanol synthesis Acetic acid synthesis Water-gas shift reaction ? ? Haber process Fischer-Tropsch synthesis The derivative Processfrom Synthesis Gas 煤液化程序之架構示意圖 Coal Liquefaction Process 劇情如何發展？ 敬請期待！