均匀实验设计在BiWO合成中的应用.docVIP

均匀实验设计在Bi2WO6合成中的应用 学生姓名： 班级： 指导老师： 【摘要】：过去制备Bi2WO6粉体，通常采用传统的固相反应法，该法设备简单、操作方便，但固颗粒的混合，只有整体的均匀性而无局部的均匀性，不能像两种流体那样可能达到完全的混合。这种方法的缺点是：(1)原料中各种组分难以混合均匀；(2)整个工艺过程易混入杂质，难以得到高纯度的粉体；(3)反应过程往往需要的温度较高(700℃)；(4)粉体颗粒大小不均匀，表面活性差，易形成团聚，致使光催化活性较低。近年来，也有一些采用新的方法制备Bi2WO6粉体的文献报道，比如水热法、微波溶剂热法和熔融的硼酸盐缓慢冷却工艺等等。 一般来说，对于制备条件的选择，必须以原料廉价易找、生产工艺简单易行、催化剂性能良好为前提，兼顾操作无毒、环境卫生、成本低廉等问题。本文以Bi(NO3)3·5H2O和Na2WO4·2H2O为原料,采用均匀实验设计方法，通过水热法合成纳米光催化剂Bi2WO6粉末。通过调节水热沉淀前驱体的pH值、反应温度、原料配比、反应时间四个因素，在表面活性剂EDTA作用下，对Bi2W06粉末样品的水热合成进行调控。随着pH值从2.5增加到11.5，Bi2WO6空间结构将逐渐转变。 关键词：均匀实验设计，纳米，Bi2WO6，水热法，光催化 指导老师签名： Abstract: In the past preparation of powder Bi2WO6, often using the traditional solid state reaction method.The method simple equipment and easy to operate, but mixture of solid particles only the overall homogeneity without local uniformity can not be done as the two kinds of fluids may reach the full mix. Disadvantage of this approach are: (1) Raw material mixing the various components is difficult; (2) The entire process easy to mix impurities, difficult to obtain high-purity powder; (3) Reaction process often requires higher temperatures ( 700 ℃); (4) Non-uniform powder particle size, surface activity is poor so easy to form a family reunion, resulting in lower photocatalytic activity. In recent years, there are some new ways of preparation Bi2WO6 powders reported in the literature, such as the hydrothermal method, microwave solvothermal method and the melting of the slow cooling process, and so on. Generally speaking, the choice of preparation conditions must be cheap and easy to find raw materials, simple process, good performance, taking into account operation of non-toxic, environmental sanitation, low-cost and other issues. In this paper, use Bi (NO3) 3 ? 5H2O and Na2WO4 ? 2H2O as raw materials to make Bi2WO6 powder. Using the uniform experimental design, by adjusting the precursor pH, reaction temperature, raw material ratio and reaction time these four factors. With the