公办药学专业《有机化学1》期末试卷22.docVIP

PAGE  PAGE 6 I Give common (or systematic) names for each of the following compounds (5 problems, 10 points): 1 2 3 4 5 II Write a structural formula for each of the following compounds( 2 points): (1) Draw a stable conformation of cis-decalin ( 十氢萘) (2) Draw a stable conformation of the following compound: III Assign R/S or Z/E configuration ( 8 points) 1 2 3 4 5 6 7 8 IV` Give structural formulas for the product or the products of the reaction (完成反应式, 15 problems, 30 points) 3 4 5 8 9 10 11 12 13 14 15 V Show how you might synthesize …from the compounds indicated and any other needed (or required) reagents (合成, 4 problems,16 points) 1 2 3 4 VI Propose a (detailed) mechanism that accounts for the following reaction ( 机理，2 problems, 8 points) 1 2 VII Write a scheme for simple chemical tests that would distinguish following 5 compounds (鉴别，6 points) Ⅷ Give a structure for A and B (推结构 ,8 points) IX Choose a letter that designates the correct order of the assigned properties: (选择, 12 points) 1 The order of stabilities(稳定性) of (1) (2) (3) (4)is A (1)(3)(2)(4) B (2)(1)(4)(3) C (3)(2)(4)(1) D (4)(2)(3)(1) 2 The order of boiling points of (1) (2) (3) (4)is A (1)(4)(2)(3) B (2)(4)(1)(3) C (3)(1)(4)(2) D (4)(2)(3)(1) 3 The order of stabilities of (1) (2) (3) (4)is A (1)(2)(4)(3) B (2)(3)(1)(4) C (3)(2)(4)(1) D (4)(1)(3)(2) 4 The order of stabilities of (1) (2) (3) (4)is A (1)(3)(2)(4) B (2)(1)(3)(4) C (3)(2)(4)(1) D (4)(3)(1)(2) 4 The order of the activities (反应活性)of (1) (2) (3) (4) in the reactions with HCl is( ) A (1)(4)(2)(3) B (2)(3)(1)(4) C (3)(1)(2)(4) D (4)(1)(3)(2) 5 Which of the following compounds is a meso compound ? ( ) Which of the following pairs of the structures represents the same compounds? ( )