公办药学专业《有机化学1》期末试卷25.docVIP

温州医学院 PAGE  PAGE 4 　 Choose a letter that designates the correct order of the assigned properties:（20%） A，A，C，B，A D，D，B，B，B Name the following compounds using common or IUPAC systematic: (10%) 1. 5-methylhexan-2-ol 2. 2-bromo-5-methylhexane 3. 4-methylpenta-1,3-diene 4. R-2-butanol 5. 4,4-dimethylcyclopentene 6. 2-methyl-5-nitrophenol 7. pent-1-yne 8.cis-1,4-dimethylcyclohexane 9. 3-ethyl-2-methylhexane 10. 1-chloro-3-nitrobenzene Predict the major product in each of the following reactions: (30%) 四、Mechanism (10%) 1. Propose a detailed mechanism for the following reactionan and explain why 3-chloro-3-methylpentane are major product. 2. Propose a detailed mechanism for the following reactionan: 首先，碳氧双键被质子化，然后6号位的双键对碳基进行亲核加成，形成碳正离子，与水反应，得到产物。 五、How would you prepare the following compounds, starting with corresponding starting materials and any other reagents needed. The procedure maybe contain several steps. (20%) 1. 2 3. 4. 5. 六、Write a scheme for simple chemical tests that would distinguish following 6 compounds（10%） 对于F的鉴别可以用D－A反应鉴别