Corrosion behaviour of powder metallurgical and cast Al–Zn–Mg base alloys.pdf

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Corrosion behaviour of powder metallurgical and cast Al–Zn–Mg base alloys.pdf

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Corrosion behaviour of powder metallurgical and cast Al–Zn–Mg base alloys

/locate/corsci Corrosion Science 46 (2004) 147–158Corrosion behaviour of powder metallurgical and cast Al–Zn–Mg base alloys A.V. Sameljuk *, O.D. Neikov, A.V. Krajnikov, Yu.V. Milman, G.E. Thompson 1 Frantsevich Institute for Problems of Material Science, 3 Krzhizhanivsky St., Kiev 03142, Ukraine Received 26 November 2002; accepted 28 May 2003Abstract The behaviour of Al–Zn–Mg base alloys produced by powder metallurgy and casting has been studied using potentiodynamic polarisation in 0.3% and 3% NaCl solutions. The influ- ence of alloy production route on microstructure has been examined by scanning electron microscopy, Auger electron spectroscopy and secondary ion mass spectrometry. An im- provement in performance of powder metallurgy (PM) materials, compared with the cast alloy, was evident in solutions of low chloride concentration; less striking differences were revealed in high chloride concentration. Both powder metallurgy and cast alloys show two main types of precipitates, which were identified as Zn–Mg and Zr–Sc base intermetallic phases. The microstructure of the PM alloys is refined compared with the cast material, which assists understanding of the corrosion performance. The corrosion process commences with dissolution of the Zn–Mg base phases, with the relatively coarse phases present in the cast alloy showing ready development of corrosion. 2003 Elsevier Ltd. All rights reserved. Keywords: Aluminium (A); Polarisation (B); SEM (B); Pitting corrosion (C)* Corresponding author. Fax: +380-44-4442131. E-mail address: leza@materials.kiev.ua (A.V. Sameljuk). 1 Corrosion and Protection Centre, University of Manchester Institute of Science and Technology, P.O. Box 88, Manchester M60 1QD, UK. 0010-938X/$ - see front matter 2003 Elsevier Ltd. All rights reserved. doi:10.1016/S0010-938X(03)00138-0 148 A.V. Sameljuk et al. / Corrosion Science 46 (2004) 147–1581. Introduction Al–Mg–Zn base alloys, with their combination of good strength, corrosion re- sistance a