乙烯基酯树脂_膨胀石墨燃料电池复合双极板.pdfVIP

乙烯基酯树脂／膨胀石墨燃料电池复合双极板 杜 超1,2，明平文，，侯 明-，傅杰·，邵志刚-， 衣宝廉- (1．中国科学院大连化学物理研究所燃料电池工程中心，辽宁大连116023；2．中国科学院研究生院，北京100039； 3．新源动力股份有限公司，辽宁大连116085；4．大连交通大学环境与化工学院，辽宁大连11602s) 摘要：采用真空浸渍结合模压的方法，选取乙烯基酯树脂(VE)和膨胀石墨(EG)板材为原料制备复合双极板。考察了微 观结构以及成型压力对双极板材料的导电性能、密封性能、机械性能以及表面亲，憎水性的影响。结果表明：随着成型 压力的增加。双极板的电阻下降；双极板的气体密封性优异。其渗透率低于2X10-6cm3，(S·∞哟。相对于原始EG板材 降低了3个数量级；复合双极板有很高的表面能。与水的接触角均大于900。这有利于电池内部液态水的排出。此外 还研究了双极板在模拟燃料电池环境下的腐蚀行为。并利用性能最优的复合双极扳组装成单电池。进行性能测试。当 电流密度达到1 500 mNcm2时。其功率密度可达到最大值670 mW／cm=。并且经200 h运行后。电池性能仍然稳定。因 此，乙烯基酯树脂／膨胀石墨复合材料是一种有前景的双极板材料。 关键词：质子交换膜燃料电池；膨胀石墨；真空浸渍；复合双极板 中图分类号：TM 911 文献标识码：A 文章编号：1002-087 X(2010)07-0667--05 Study on vinyl ester resin／expanded graphite composite bipolar plates for proton exchange membrane fuel cells DU Chao”，MING Ping-wen3，HOU Min91，FU Jie4，SHAO Zhi-gan91，YI Bao-lianl “．Fud Cell System and Engineering Research Group，Dalian Institute ofChemical Physics,Chinese Academy ofScience,Dalian Liaoning l 16023，China；2．Graduate School ofthe Chinese Academy ofScieaces,B啕ing 100039,China；3．Sunrise Power Co．Ltd,Dalian Liaooing 1 J6085，China；4．Env面onmental and Chemical Engineering Department,Dalian Jiaotong University,Dalian Liaoning J 16028，a血aJ Abstract：In this pap6r．composite bipolar plates were prepared with、，irlyI ester resin(、，E)and expslllded graphite (EG)sheets by the method of resin vacuum impregnation and compression molding．n胃effects of micrestnclure and molding pressure on the electrioal property， gas permeabil谴y。盯Iechani∞I propety and hydrophobicity／hydroph,跳y worG investigated．The resu峙show that with the ircrease of moacaxj pressure。the resistance of composne bipolar plate was reduced．Compared with the raw EG sheets。its gas i删lily is lower than 2 X 1 0-8 cma／(S‘姗2)．which is reduced by three ordem of magnitude．Cunpes舱bipolar plate has high surface energy and its contact angle with water is greater than 90*，which makes the删water in the cell easay to be swept away．In addition。the corrosion behavior of№bqx-ar paate in a simulated fuel cell envi删was also