铁砷新超导的合成_闻海虎探究.pdfVIP

铁基超导体专题 铁砷新超导材料的合成研究 ＊ 闻海虎 　　牟 　刚 　　祝熙宇 　　韩 　飞 　　程 　鹏 　　沈 　冰 　　曾 　斌 (中国科学院物理研究所 　北京凝聚态物理国家实验室 　北京 　100190) 摘 　要 　 　文章简单介绍了作者在铁砷基材料的 合成方面所取得 的一系 列工作 进展 .首先介 绍了在 空穴型 掺杂的 1111 系统中发现超导电性的工作以及后续的发展 .然后介绍了在氟基铁砷材料 AeFeA sF (Ae=S r, Ca , Ba 和 Eu)方 面所取得的进展以及最新的超导转变温度的记录 .最后介 绍一种铁砷 面间距较 大的新型结 构材料(Sr3 Sc2O 5)Fe2 A s2 的合成以及一种新型超导体(Sr4 V 2O 6)F e2 A s2(T c =37 .2 K)的发现 . 关键词 　　铁砷材料 , 新超导体 The synthesis of new FeAs-based superconductors WEN Hai-Hu 　　M U G ang 　　ZH U Xi-Yu 　　HA N Fei CHENG Peng 　　SHEN Bing 　　ZENG Bin (Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences , Beijing　100190, China) Asbtract 　　 We report our progress in the synthesis of new compounds and superconductors in the FeA s- based family .First , we found superconductivity in hole-doped oxy-arsenide La1 -x Srx FeA sO and P r1 -x SrxFeA sO .T he Hall effect confirmed the hole charge carriers .H c2(T)is higher in the hole doped samples compared with the electron doped ones .This is attributed to the higher density of states in the hole doped side .Secondly , we present some results of the fluorine -derivative parent phases SrFeA sF , CaFeAsF and EuFeA sF which we discovered independently .By doping the system with electrons , we observed supercon- ductivity (onset point of resistivity)at about 32 K for Sr0.6 La0 .4 FeA sF , 52 .8 K for Ca0.6 Pr0 .4 FeA sF , and 57 .4 K for Ca0.6 N d0 .4 FeA sF .Finally , we report the discovery of a new compound (Sr3 Sc2 O5 )Fe2 As2 .We have also successfully fabricated a new superconducto r (Sr4 V 2O 6 )Fe2 As2 (with