注浆成型法制备氧化钇稳定的氧化锆透氧膜及其性能.PDFVIP

第43 卷第6 期 硅 酸 盐 学 报 Vol. 43 ，No. 6 2 0 1 5 年 6 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY June ，2015 DOI ：10.14062/j.issn.0454-5648.2015.06.12 注浆成型法制备氧化钇稳定的氧化锆透氧膜及其性能 沈 斌，邹星礼，程红伟，赖冠全，鲁雄刚 (上海市现代冶金与材料制备重点实验室，上海大学，上海 200072) 摘 要：采用注浆成型法制备8% (摩尔分数)氧化钇稳定氧化锆(8YSZ)透氧膜，分析浆料特性、烧结特性和电学性能并将其 用于固体透氧膜(SOM)法制备金属。结果表明：当添加4%(质量分数)柠檬酸作为8YSZ 浆料分散剂时，浆料相对黏度为 1.82， Zeta 电位为–43.7 mV 。透氧膜素坯经1 700 ℃煅烧2 h 后，物相全部转化为立方相，相对密度达到99.1% 。在500 ℃时，1 700 ℃ 烧结成型的透氧膜总电阻最小，为 149.38Ω ，总电导率最大，为5.84×10–4 S/cm。该法制备的膜管经SOM 法电解脱氧实验证 明具有优良的控氧性能和抗熔盐侵蚀特性。 关键词：注浆成型法；氧化钇稳定的氧化锆透氧膜；固体透氧膜法；熔盐电解 中图分类号：TQ174.62; TQ174.12 文献标志码：A 文章编号：0454–5648(2015)06–0781–07 网络出版时间： 网络出版地址： Preparation of Yttria Stabilized Zirconia Oxygen Ion Conducting Membrane by Slip Casting Method and Its Properties SHEN Bin, ZOU Xingli, CHENG Hongwei, LAI Guanquan , LU Xionggang (Shanghai Key Laboratory of Modern Metallurgy and Materials Processing, Shanghai University, Shanghai 200072, China) Abstract: The 8% (in mole) yttria stabilized zirconia (8YSZ) oxygen ion conducting membranes were prepared by a slip casting method. The properties of slurry, sintering and electrical were investigated and the membranes were used in the solid oxide membrane (SOM) process to produce metals. The results show that the relative viscosity and the Zeta potential of the 8YSZ slurry are 1.82 and –43.7 mV, respectively, at citric acid of 4 % (in mass) as a dispersant. The phase of the 8YSZ membrane sintered at 1 700 ℃ for 2 h transforms into a cubic phase completely, and the relative density is 99.1 %. The 8YSZ membrane sintered at 1 700 ℃ possesses