变压器油中活性硫测试方法的研究毕设论文.doc

PAGE  CHANGSHA UNIVERSITY OF SCIENCE TECHNOLOGY 毕业论文 题目：变压器油中活性硫测试方法的研究 变压器油中活性硫测试方法的研究 学生姓名： 何 维 民 学 号： 200967090124 班 级： 应化09-01 所在院(系): 化学与生物工程学院 指导教师： 汪红梅 完成日期: 2013/6/11  变压器油中活性硫测试方法的研究 电力变压器绝缘油含硫测试方法的研究 摘要 本文采用艾氏卡法、库仑法和高频红外法对变压器活性硫进行测定，调整测定条件。通过以白油为基础油，加入含活性硫的2-正丁基硫醚试剂配制一系列质量浓度的标准样品，参照ASTM－D－1275(B)法的实验条件，优化铜粉与样品的反应时间，在200℃下样品与铜粉反应2.5h，分别测定与铜粉反应前和与铜粉反应后的各样中的全硫。 关键词：变压器油；活性硫测定；库仑法；高频红外法 research ON Power transformer insulation oil sulfur-containing test method ABSTRACT In order to determine the corrosive sulfur in transformer, the feasibility of the three methods ,that is eschkal method、coulomb method and the infrared absorption of sulfur detection method ,was measured by the sample standard addition recovery． A series of different quality concentration of standard sample were made by adding the active sulphur reagent．With the reference to the experimental conditions of the ASTM－D－1275(B) method，it was reacted with copper powder at 30h under 140℃，the total sulfur of unreaction and reaction with copper powder was determined.Compared to the sulfur recovery of all sample，it showed that the infrared absorption of sulfur detection method was the best method for determining the total sulfur in the insulation oil of transformer，It puts a new way on the determination of sulfur corrosion in power transformer． Key words: Transformer insulation oil；Corrosive sulfur determination；Standard addition recovery；The infrared absorption of sulfur detection method  目录  TOC \o 1-3 \h \z \u  HYPERLINK \l _Toc295299960 1 绪论  PAGEREF _Toc295299960 \h 1  HYPERLINK \l _Toc295299961 1.1 选题目意义  PAGEREF _Toc295299961 \h 1  HYPERLINK \l _Toc295299962 1.2 硫测定方法的现状及趋势  PAGEREF _Toc295299962 \h 1  HYPERLINK \l _Toc295299963 1.2.1 煤中全硫的测定方法  PAGEREF _Toc295299963 \h 2  HYPERLINK \l _Toc295299964 1.2.2 油中全硫的测定方法  PAGERE