聚丙烯聚酰亚胺复合材料的研究学位论文.docVIP

PAGE  PAGE \* MERGEFORMAT36 聚丙烯/聚酰亚胺复合材料的研究 摘要：本文以聚丙烯为主要研究对象，制备PMDA-ODA型聚酰亚胺，采用聚酰亚胺粉末或聚酰胺酸溶液改性聚丙烯。通过改变聚酰亚胺的分子量和添加量，经过挤出、注塑，从而得到不同聚集态结构和性能的聚丙烯/聚酰亚胺复合材料。 对制备的复合材料进行各种性能测试和结构表征：红外、偏光显微镜、XRD、扫描电镜、拉伸测试、冲击测试和维卡软化点。研究发现，聚酰亚胺的加入会不同程度的降低聚丙烯的结晶度；聚丙烯/聚酰亚胺的聚集态结构和性能受聚酰亚胺分子量和添加量的影响，分子量、添加量过大或过小都不利于复合材料规整结晶结构的形成。当用溶液改性时会出现分子链降解和环化情况。用粉末改性的配比为100：0.2时的中分子量所制备的复合材料的聚集态结构最为规整，结晶最为完善，晶体数目最多，且球晶尺寸较小，大小均匀，综合性能最好。 关键词：聚酰亚胺，聚集态，分子量，添加量 Research of PP/PI Composite Materials Abstract In this paper, the Polypropylene (pp) is the object of study by adding the type PMDA-ODA of polyimide, To adopt Modified powder and Modified solution to prepare PP/PI composite materials. They got diffrent aggregation structure and properties of These Composite materials by the polytechnic of supplant and syringe which is under The condition of different molecular weight and different ratio. Testing the composite materials performance and characterizing their structure. Found that the addition of polyimide can induce the polyproylene molecules crystallize in various degree. The aggregation structure and properties of PP/PI composite materials can be effected by the molecular weight and ratio. The molecular weight and ratio that not too high or too slow is conducive to the formation of the crystallographic of the composite material. The molecular chain will degradation and cylization when the solution of PAA is modified. When using PI powder to modified PP under ratio of 100：0.2，the compound materials can get the most neat aggregation structure ,the most perfect crystalloid, the largest number of spherulite size and smaller, uniform size, the best properties as well. 目录  TOC \o 1-3 \u  1 前言  PAGEREF _Toc296418363 \h 1 1.1聚丙烯  PAGEREF _Toc296418364 \h 1 1.1.1概述  PAGEREF _Toc296418365 \h 1 1.1.2改性及研究现状  PAGEREF _Toc296418366 \h 2 1.2聚酰亚胺  PAGEREF _Toc296418367 \h 5 1.2.1概述  PAGEREF _Toc296418368 \h 5 1.2.2国内外发展状况  PAGEREF _Toc296418369 \h 7 1.3选题的意义及目的  PAGEREF _Toc296418370 \h