第六章2：传感器件_93801499探讨.ppt

有机器件2：传感器件;　　　　　碳氢化合物传感器 醇传感器　　　　　二氧化碳传感器　　　　　湿度传感器件　　　　　味道传感器　　　　　; 基本原理;光纤传感器的优点; 实物照片; 特殊用途;;电化学识别;偶合反应体系;如果主体（H)与客体（G)形成1：1的配合物。则配合物的稳定性常数用下面的表达式表示：;K+ 0, 2:1, 1:1 CH2Cl2;Electrochemical behavior of hemin and PEO-hemin in ion-conductive polymer matrices;Electrochemical detection of dioxygen and hydrogen peroxide by hemin immobilized on chemically converted graphene ;UV-visible spectra of hemin, CCG and CCG-hemin dissolved or dispersed in 52.8 mmol L?1 ammonia solution. The concentrations of hemin and CCG are 5×10?3 mmol L?1 and 10.00 mg L?1, respectively. The CCG-hemin mixture contains 5×10?3 mmol L?1 hemin and 10.00 mg L?1 CCG. ;AFM images of CCG (left) and CCG-hemin (right) complex sheets on mica;Cyclic voltammograms of (A) CCG, hemin and CCG-hemin modified electrodes, the first and 100 th cycles of (B) hemin and (C) CCG-hemin modified electrodes in 0.5 mol L?1 H2SO4 solutions saturated with N2. Scan rate=100 mV s?1. ;Cyclic voltammograms of CCG, hemin and CCG-hemin modified electrodes in 0.5 mol L?1 H2SO4 solutions saturated with O2. Scan rate=100 mV s?1.;RDE voltammograms of CCG, hemin and CCG-hemin modified electrodes at a scan rate of 50 mV s?1 and a rotation rate of 900 rpm in O2 saturated 0.5 mol L?1 H2SO4 solutions.;(A) The RDE voltammograms of CCG-hemin modified electrode at different rotating rates in O2 saturated 0.5 mol. L?1 H2SO4 solutions. Scan rate = 50 mV s?1. (B) Koutecky -Levich plot of j?1 vs. ω?1/2 obtained from the RDE data of (a) at ?0.40 V and ?0.50 V. The dashed lines are calculated for the diffusion-convection controlled reduction of O2 via 2 (n = 2) or 4 (n = 4) electrons.;Cyclic voltammograms of CCG-hemin modified electrode in 0.5 mol L?1 H2SO4 solution bubbled with O2 for different time. Scan rate=100 mV s?1. ;Cyclic voltammograms of CCG, hemin and CCG-hemin modified electrodes in 0.5 mol L?1 H2SO4 solutions containing 1.44 mmol L?1 H2O2. Scan rate=100 mV s?1. ;(A) Cyclic voltammograms of CCG-hemin modi