一种高效环保型阻垢缓蚀剂的制备及性能研究一种高效环保型阻垢缓蚀剂的制备及性能研究.docVIP

PAGE  PAGE 8 一种高效环保型阻垢缓蚀剂的制备及性能研究 摘要：以无水马来酸酐和β-巯基丙酸为主要原料、铬酸钾为催化剂合成出S-羧乙基硫代琥珀酸(CETSA)，并对其阻垢缓蚀效果进行了研究。结果表明：S-羧乙基硫代琥珀酸具有良好的水溶性和生物降解性，在宽pH范围内具有较好的缓蚀阻垢性能，尤其将其与葡萄糖酸钠、丙烯酸羟丙酯（HPA）及Zn盐等物质复配后（无磷1#），其缓蚀率得到大幅度提高。它在45℃和投加浓度为20ppm条件下，其缓蚀率可达93.2%、阻垢率达98.5%，且无磷环保，具有更高的性价比。 关键词：无磷环保型；缓蚀阻垢剂； S-羧乙基硫代琥珀酸；合成 中图文分类号：TQ085 文献标识码:A Preparation and Study of a New kind of Phosphorus-free Corrosion and Scale Inhibitor Zeng De-fang, Xiao Jian-guo (School of Resource and Environmental Engineering, Wuhan University of Technology; Hubei Key Lab of Mineral Resource Processing and Environment; Wuhan, Hubei 430070, P.R.China) Abstract：Experimental process of preparing S-carboxymethyl thiosuccinate acid（CETSA） is described, in which anhydrous maleic anhydride and β-mercaptopropionic acid are used as the main raw material and catalyst such as potassium chromate was used. Its scale and corrosion inhibition performance has been studied compound with other water treatment. Result shows that CETSA has a good water-soluble、bio-degradability, and has a good scale and corrosion inhibition ability within a wide range of pH values. When compound with sodium gluconate, hydroxypropyl acrylate (HPA) and Zn salt, the performance has obviously enhanced. Under the condition of 45℃，dosage of 20 mg·L-1, the corrosion inhibition rate can reach up to 93.2% , and its scale inhibition rate can reach up to 98.5%. In addition, the formula is Phosphorus—Free，so it has a much more higher ratio of quality to value. Keywords：phosphorus-free and environmentally friendly type; Corrosion and Scale Inhibitor; carboxymethyl thiosuccinate acid; synthesis  随着能源电力和钢铁工业工业的迅猛发展，循环冷却水的用量也来越大，为了防止循环冷却水所引起的管道腐蚀和结垢等不良现象，通常需向循环冷却水中加入一定量的阻垢缓蚀剂，以防止管道腐蚀和结构，但传统的阻垢缓蚀剂中因含有磷酸盐类等物质，排入环境会引起水体富营养化，严重污染水环境。因此如何研制出一种新型无磷阻垢缓蚀剂已成为当今环保和水处理剂领域亟待解决的重大课题[1-2]。为此，本文采用新的合成方法制备出环保型无磷阻垢缓蚀剂—S-羧乙基硫代琥珀酸，然后再将其与其他无磷阻垢剂和缓蚀剂复配，得到性能更加优异的新型无磷阻垢缓蚀剂，展现出良好的应用前景[3]。 1.实验部分 1.1 主要实验药品与仪器 马来酸酐、β-巯基丙酸、甲苯、冰醋酸、铬酸钾、葡萄糖酸钠、苯甲酸钠、水解聚马来酸酐（HPMA）、ZnSO4·7H2O、CaCl2、MgS