Fe[SeTe]单晶中出现起始转变温度为14.6K超导电性.pptVIP

Fe(SeTe)单晶中出现起始转变温度为14.6K的超导电性和过量Fe发挥的的作用。 赵旭鹏 ;直至今日，对于铜基超导材料的高温超导机制，物理学界仍未形成一致看法，这也使得高温超导成为当今凝聚态物理学中最大的谜团之一。因此很多科学家都希望在铜基超导材料以外再找到新的高温超导材料，从而能够使高温超导机制更加明朗。 2008年Hosono等发现LaFeAsO 1-x F x 具有26K的超导转变之后，全世界掀起了一股铁基超导热。 Fe1+ySexTe1-x体系具有结构简单、不含As、容易生长较高质量的单晶的优点。; Single crystal was successfully grown by self-?ux method, and effect of post-annealing technique on structure and superconelfductivity was also systemically studied. The results show the as-grown sample has an excellent superconductivity with an onset transition temperature Tconset ~14.6 K and a zero resistivity temperature Tczero~13.4 K. After annealing at 400 C for 48 h, excess Fe in the post-annealing sample appears with Fe1.06Se0.34Te0.66 formula, and superconductivity was strongly suppressed with Tczero~8.0 K. The experiments found that excess Fe is located at Fe(2) site with local magnetic moment. ;According to the Werthamer-Helfand-Hohenberg(WHH) theory, the upper critical ?elds Hc2 at zero temperature were estimated to be 54.2T for as-grown sample and 28.2 T for post-annealing sample. Two abnormal drops in DC magnetization are found near 40 K and 125 K for all samples, the one near 40K may be related to a spin freezing of excess Fe and that near 120K should be corresponding to the structural transition from tetragonal to monoclinic. This is con?rmed by the strain measurement. On the other hand, a kink change of speci?c heat was also found around 10K for a post-annealed sample. ;我们对采用自助溶剂法生长得到的Fe1.01Se0.38Te0.62单晶和退火技术对于材料结构和超导电性的影响进行了系统的研究。研究结果表明制备出的生成态晶体样品有着优良的超导特性，起始转变温度为 14.6 K，零电阻率温度为 13.4 K .在400℃ 下退火48小时,退火后样品中过量的Fe 的比例为Fe1.06Se0.34Te0.66，超导电性将明显出现在零电阻率温度Tczero =8.0 K。 实??发现过量的Fe处于Fe(2)位并造成局域磁矩。根据WHH理论，在零电阻处的生成态样品上临界磁场估计达到了54.2T，退火后达到了28.2 T。在所有样品的直流磁化曲线中发现了两个异常的下降，分别在40K到125 K。40 K附近的下降可能与过量的Fe的自旋冻结有关,而117K附近的下降应该对应于从正方到单斜的结构性转