粉煤灰论文粉煤灰制备沸石负载CuOCeO2催化氧化染料废水研究.doc

粉煤灰论文：粉煤灰制备沸石负载CuO/CeO_2催化氧化染料废水研究 【中文摘要】粉煤灰是火力发电厂的废弃物,每年的堆积量占用了很大的空间。沸石是一种性能优良的材料,已经广泛应用于农业、石化、吸附环保、化学等领域。由于粉煤灰和沸石在组成上的相似,因此可以利用粉煤灰制成粉煤灰沸石。本文首先以粉煤灰为原料,通过碱熔-水热合成法制备了粉煤灰沸石。采用正交试验设计法,讨论了m(灰)/m(碱)比、m(灰)/m(水)比、煅烧温度和晶化时间对出水中色度和COD指标的影响,从而确定制备粉煤灰沸石的工艺条件。制备的粉煤灰沸石经XRD表征,确定为NaA型沸石相。其次是催化剂的制备,确定以粉煤灰沸石为载体负载CuO/CeO2的工艺条件。先采用正交试验设计法,讨论了m(粉煤灰沸石)/V(硝酸铜)比、硝酸铜浓度、煅烧温度和焙烧时间对出水中色度和COD指标的影响,从而确定制备粉煤灰沸石负载CuO的工艺条件。后采用单因素法确定粉煤灰沸石为载体负载CuO/CeO2的工艺条件。最后,以过氧化氢为氧化剂,粉煤灰沸石为载体负载CuO/CeO2催化氧化酸性大红GR废水和活性艳红X-3B废水。先后讨论了负载CuO/CeO2的粉煤灰沸石催化剂投加量、过氧化氢投加量、废水pH值、反应时间、反应温度对酸性大红GR废水、活性艳红X-3B废水处理效果的影响。最终确定了酸性大红GR废水、活性艳红X-3B废水的最佳处理工艺条件。 【英文摘要】Coal fly ash is a kind of waste from the thermal power plant and occupy a large amount of space every year.Zeolite is an execelent material and has been widely applied in agriculture,petrochemical,environmental adsorption,chemical and other fields.The coal fly ash and zeolite have the similar composition,so the zeolite can be made by coal fly ash.Firstly, this thesis used the coal fly ash as raw materials to make the zeolite by alkali fusion-hydrothermal synthesis. Using the method of orthogonal experimental design to determine the craft condtion of the coal fly ash zeolite.The effects of ratio of ash to alkali,ratio of ash to water,calcination temperrture and crystallization time on the color and COD indexes in effluent were discussed.The synthesized coal fly ash zeolite was confirmed to be NaA type of zeolite phase by XRD measurement.Secondly,the catalyst was prepared.Determining the craft condition of the coal fly ash zeolite as a carrier loaded copper oxide and cerium oxide. Using the method of orthogonal experimental design,the effects of ratio of coal fly ash zeolite to copper nitrate,copper nitrate concentration,calcination temperrture and calcination time on the color and COD indexes in effluent were discussed.Then the craft condition of the coal fly ash zeolite loaded copper oxide was determinined.Then d