杂多酸催化剂选编.ppt

杂多酸 催化剂;杂多酸分子结构;杂多酸分子结构;杂多酸分子结构;杂多酸酸性;杂多酸酸性;杂多酸的负载 ;负载在介孔分子筛上的杂多酸 ;杂多酸上的多相催化反应 ;介孔材料酸碱功能化; Notable in the context of catalysts based on mesoporous silica phases are efforts to create solid-state acids that could be used a heterogeneous acid catalysts, in analogy to Br?sted acidic zeolites。 As they possess larger pores they should be able to incorporate larger substrates. ;介孔材料酸碱功能化; An interesting approach to the introduction of sulfonic acid groups into SBA-15 phases. obtain materials by functionalization with a bissilylated disulfide reagent followed by cleavage of the disulfide bridges and oxidation of the resulting thiols into sulfonic acid groups. This results in a material in which each two of the sulfonic acid groups possess a specific spatial separation from one another. ;----T. V. Kovalchuk, H. Sfihi, A. S. Korchev, A. S. Kovalenko, V. G. Il’in, V. N. Zaitsev, and J. Fraissard， J. Phys. Chem. B 2005, 109, 13948-13956;Assembly of Heteropoly Acid Nanoparticles in SBA-15 and Its Performance as an Acid Catalyst ----Shu-Yuan Yu, Li-Ping Wang, Bo Chen, Ying-Ying Gu, Jing Li, Han-Ming Ding, and Yong-Kui Shan， Chem. Eur. J. 2005, 11, 3894– 3898;介孔材料酸碱功能化;Mesoporous silica materials have also been employed in the development of heterogeneous base catalysts. A comprehensive survey of work up to 2000 may be found in a review by Weitkamp et al. Two more recent studies have dealt with the role of the solid support materials of the actual active catalytic species and the effectiveness of these species in relation to the quality of their dispersion in the support material. ;介孔材料酸碱功能化;介孔材料酸碱功能化; A novel bifunctional mesoporous material MA/SBA-15 has been synthesized in one pot by in situ introduction of aluminium and magnesium salts and controlling the synthesis conditions, with the framework insertion of aluminium and high dispersion of magnesia resulting in both the strong basic and acidic sites being simultaneously formed on SBA-15. ----L. Y. Shi, Y. M. Wang,